Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 16, Problem 40E
Interpretation Introduction
To describe: The equations depicting the amphoteric nature of
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment?
a) the heat capacity of the calorimeter
b) Mass of sample
c) Ti
d) The molarity of the HCl
e) Tf
Predict products for the Following organic rxn/s by
writing the structurels of the correct products. Write
above the line provided"
your answer
D2
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+
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Spark
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4 CH 3 11
3 CH 3 (CH2) 4 C-H + CH3OH
CH2 CH3 + CH3 CH2OH
0
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C43
+ 2 KMn Dy→→
C-OH
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1110
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=C
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+ HNO 3
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2
Chapter 16 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 16 - Prob. 1SAQCh. 16 - Q2. Which pair is a Brønsted–Lowry conjugate...Ch. 16 - Prob. 3SAQCh. 16 - Prob. 4SAQCh. 16 - Q5. An HNO3(aq) solution has a pH of 1.75. What is...Ch. 16 - Q6. Find the pH of a 0.350 M aqueous benzoic acid...Ch. 16 - Q7. Find the pH of a 0.155 M HClO2(aq) solution....Ch. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - Prob. 11SAQCh. 16 - Prob. 12SAQCh. 16 - Prob. 13SAQCh. 16 - Prob. 14SAQCh. 16 - Q15. Which acid has the largest Ka: HClO2(aq),...Ch. 16 - 1. What causes heartburn? What are some possible...Ch. 16 - 2. What are the general physical and chemical...Ch. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - 11. What are diprotic and triprotic acids? List an...Ch. 16 - 12. Define the acid ionization constant and...Ch. 16 - 13. Write an equation for the autoionization of...Ch. 16 - 14. What happens to the [OH–] of a solution when...Ch. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - 22. How can you determine if an anion will act as...Ch. 16 - 23. What is the relationship between the acid...Ch. 16 - 24. What kinds of cations act as weak acids? List...Ch. 16 - 25. When calculating the [H3O+] for a polyprotic...Ch. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 -
31. What is acid rain? What causes it, and where...Ch. 16 - Prob. 32ECh. 16 - 33. Identify each substance as an acid or a base...Ch. 16 - 34. Identify each substance as an acid or a base...Ch. 16 - 35. In each reaction, identify the Brønsted–Lowry...Ch. 16 - Prob. 36ECh. 16 - 37. Write the formula for the conjugate base of...Ch. 16 - 38. Write the formula for the conjugate acid of...Ch. 16 - 39. Both H2O and H2PO4– are amphoteric. Write an...Ch. 16 - 40. Both HCO3– and HS– are amphoteric. Write an...Ch. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - 47. Calculate [OH–] in each aqueous solution at 25...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - 50. Calculate [H3O+] and [OH–] for each solution...Ch. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - 53. Like all equilibrium constants, the value of...Ch. 16 - Prob. 54ECh. 16 - 55. Calculate the pH of each acid solution....Ch. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - 58. Determine the pH of each solution.
a. 0.048 M...Ch. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - 61. What is the pH of a solution in which 224 mL...Ch. 16 - Prob. 62ECh. 16 - Prob. 63ECh. 16 - 64. Determine the [H3O+] and pH of a 0.200 M...Ch. 16 - 65. Determine the pH of an HNO2 solution of each...Ch. 16 - 66. Determine the pH of an HF solution of each...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - 71. Determine the percent ionization of a 0.125 M...Ch. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Prob. 78ECh. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Prob. 88ECh. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - 97. Determine the [OH–] and pH of a solution that...Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. Determine if each salt will form a solution...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - 105. Determine the pH of each solution.
a. 0.10 M...Ch. 16 - 106. Determine the pH of each solution.
a. 0.20 M...Ch. 16 - Prob. 107ECh. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - 112. Calculate the [H3O+] and pH of each...Ch. 16 - 113. Calculate the concentration of all species in...Ch. 16 - 114. Calculate the concentration of all species in...Ch. 16 - 115. Calculate the [H3O+] and pH of each H2SO4...Ch. 16 - Prob. 116ECh. 16 - Prob. 117ECh. 16 - Prob. 118ECh. 16 - 119. Based on their molecular structure, pick the...Ch. 16 - Prob. 120ECh. 16 - Prob. 121ECh. 16 - 122. Which is a stronger base, PO43– or AsO43–?...Ch. 16 - 123. Classify each species as either a Lewis acid...Ch. 16 - 124. Classify each species as either a Lewis acid...Ch. 16 - Prob. 125ECh. 16 - Prob. 126ECh. 16 - Prob. 127ECh. 16 - Prob. 128ECh. 16 - Prob. 129ECh. 16 - Prob. 130ECh. 16 - Prob. 131ECh. 16 - Prob. 132ECh. 16 - 133. Acid rain over the Great Lakes has a pH of...Ch. 16 - 134. White wines tend to be more acidic than red...Ch. 16 - 135. Common aspirin is acetylsalicylic acid, which...Ch. 16 - Prob. 136ECh. 16 - Prob. 137ECh. 16 - Prob. 138ECh. 16 - Prob. 139ECh. 16 - 140. Determine the pH of each two-component...Ch. 16 - Prob. 141ECh. 16 - Prob. 142ECh. 16 - 143. The pH of a 1.00 M solution of urea, a weak...Ch. 16 - 144. A solution is prepared by dissolving 0.10 mol...Ch. 16 - 145. Lactic acid is a weak acid found in milk. Its...Ch. 16 - Prob. 146ECh. 16 - Prob. 147ECh. 16 - Prob. 148ECh. 16 - Prob. 149ECh. 16 - 150. To what volume should you dilute 1 L of a...Ch. 16 - Prob. 151ECh. 16 - Prob. 152ECh. 16 -
153. Calculate the pH of a solution prepared from...Ch. 16 - 154. To 1.0 L of a 0.30 M solution of HClO2 is...Ch. 16 - 155. A mixture of Na2CO3 and NaHCO3 has a mass of...Ch. 16 - 156. A mixture of NaCN and NaHSO4 consists of a...Ch. 16 - 157. Without doing any calculations, determine...Ch. 16 - 158. Without doing any calculations, determine...Ch. 16 - Prob. 159ECh. 16 - 160. Without using a calculator, determine the pH...Ch. 16 - Prob. 161QGWCh. 16 - Prob. 162QGWCh. 16 - Prob. 163QGWCh. 16 - Prob. 164QGWCh. 16 - Prob. 165QGWCh. 16 - 166. Sulfur dioxide protects wine from spoiling;...
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- When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.arrow_forwardQ6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of the two bases shown (on the -NH2). Include curved arrows to show the mechanism. O₂N- O₂N. -NH2 -NH2 a) Which of the two Bronsted bases above is the stronger base? Why? b) Identify the conjugate acids and conjugate bases for the reactants. c) Identify the Lewis acids and bases in the reactions.arrow_forwardQ5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forward
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- Q5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forwardWhat is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forward
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