(a) Interpretation: The common name of the given structure of amine is to be stated. Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is R − NH 2 . Amines can be classified as primary amine, secondary amine, and tertiary amine. In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group. In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group. In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 1

Question

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Answer 2

Question

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 3

Question

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 4

Question

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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Answer 5

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 6

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 7

Chapter 16, Problem 16.7E

Interpretation Introduction

(a)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The common name of the given structure of amine is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is R−NH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16 - Prob. 16.1E Ch. 16 - Prob. 16.2E Ch. 16 - Prob. 16.3E Ch. 16 - Prob. 16.4E Ch. 16 - Prob. 16.5E Ch. 16 - Prob. 16.6E Ch. 16 - Prob. 16.7E Ch. 16 - Prob. 16.8E Ch. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....

Solution Summary: The author explains that the common name of the structure of amine is isopropylamine.

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Chapter 16 Solutions