(a) Interpretation: The structure of the benzamide is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature . The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name. Rules for writing IUPAC name from the structural formula are: • First, identify the longest carbon chain. • The next step is to identify the groups attached to the longest chain. • Identify the position, location, and a number of the substituents bonded to the carbon chain. • Use prefix di, tri, tetra if the same type of substituents is present. • Name the substituents in alphabetical order.

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Answer 1

Question

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

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Answer 2

Question

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 3

Question

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 4

Question

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 5

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 6

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 7

Chapter 16, Problem 16.47E

Interpretation Introduction

(a)

Interpretation:

The structure of the benzamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the N-methylethanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the N-methyl-3-phenylbutanamide is to be drawn.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 12

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Answer 14

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Answer 15

Ch. 16 - Prob. 16.1E Ch. 16 - Prob. 16.2E Ch. 16 - Prob. 16.3E Ch. 16 - Prob. 16.4E Ch. 16 - Prob. 16.5E Ch. 16 - Prob. 16.6E Ch. 16 - Prob. 16.7E Ch. 16 - Prob. 16.8E Ch. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....

Solution Summary: The author explains the systematic naming of organic compound by IUPAC nomenclature. The structure of the benzamide is shown below.

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Chapter 16 Solutions