(a) Interpretation: The IUPAC name of the given amide is to be stated. Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature . The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name. Rules for writing IUPAC name from the structural formula are: • First, identify the longest carbon chain. • The next step is to identify the groups attached to the longest chain. • Identify the position, location, and a number of the substituents bonded to the carbon chain. • Use prefix di, tri, tetra if the same type of substituents is present. • Name the substituents in alphabetical order.

Question

Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5

Answer 1

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Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5

A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol b. 3,4-Dimethyl-1-pentanol c. 4-Ethyl-2-heptanol d. 5,7-Dichloro-3-heptanol

What is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?

Answer 2

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Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 3

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Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 4

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Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

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Answer 5

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Answer 6

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Answer 7

Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 8

Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 9

Chapter 16, Problem 16.45E

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 10

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 11

Interpretation Introduction

(b)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 12

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 13

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 14

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 15

Interpretation Introduction

(d)

Interpretation:

The IUPAC name of the given amide is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are:

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents is present.

• Name the substituents in alphabetical order.

Answer 16

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Ch. 16 - Prob. 16.1E Ch. 16 - Prob. 16.2E Ch. 16 - Prob. 16.3E Ch. 16 - Prob. 16.4E Ch. 16 - Prob. 16.5E Ch. 16 - Prob. 16.6E Ch. 16 - Prob. 16.7E Ch. 16 - Prob. 16.8E Ch. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....

Solution Summary: The author explains how the IUPAC name of the given amide is to be stated.

Chapter 16 Solutions