ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 16, Problem 16.63AP
Interpretation Introduction

Interpretation:

The resonating structures of carbocation intermediate formed in furan in Friedel crafts acylation reaction are to be drawn. Whether Friedel crafts acylation occurs at carbon -2 or carbon -3 in furan is to be stated.

Concept introduction:

Friedel crafts acylation reaction is a reaction in which an aromatic compound is reacted with an acyl chloride in the presence of a Lewis acid to form an aromatic ketone. This reaction takes place by electrophilic substitution reaction meachanism.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Chapter 16 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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