(a) Interpretation: The predominant product that is obtained from the monosulfonation of m − bromotoluene is to be predicted. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 3

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 4

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 5

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 6

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that the predominant product obtained from the monosulfonation of m-bromotoluene is to be predicted.

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