(a) Interpretation: The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated. Concept introduction: Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 1

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 3

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 4

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 5

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 6

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 7

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that electrophilic substitution reactions are reactions in which electron loving species get substituted on a benzene ring.

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Chapter 16 Solutions