(a) Interpretation: The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated. Concept introduction: Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 1

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 3

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 4

Question

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answer 5

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 6

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 7

Chapter 16, Problem 16.24P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that electrophilic substitution reactions are reactions in which electron loving species get substituted on a benzene ring.

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Chapter 16 Solutions