ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 16, Problem 16.24P
Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(c)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(d)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

Interpretation Introduction

(e)

Interpretation:

The product formed on reaction of the given reactant on bromination is to be stated. Whether the substituent in the given reactant is ortho, para directing or meta directing is to be stated.

Concept introduction:

Electrophilic substitution reactions are reactions in which electrophile, that are electron loving species get substituted on a benzene ring. The benzene ring should have an electron donating group that makes the ring nucleophilic, that is electron rich for the electrophile to attack.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…
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Chapter 16 Solutions

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