EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
6th Edition
ISBN: 9781319385415
Author: PARISE
Publisher: VST
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Chapter 16, Problem 16.33P
Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from CH sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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C. I, II, III Consider the reaction sequence below to answer the following questions: 0 0 1. NaOEt, EtOH ΕΙΟ OEt 2 Compound X CO₂Et NaOEt, EtOH CO₂Et Br Compound Y A Compound Z A. Compound X, diethyl propanedioate, is more commonly known as a. ethyl acetoacetate acetoacetic ester b. C. oxalic ester d. malonic ester B. Write the complete stepwise mechanism for the conversion of Compound X into Compound Y. Show all electron flow with arrows and draw all intermediate structures.
Diethyl malonate can be prepared by the following reaction sequence. Draw the structures of each of the missing intermediates in the boxes provided EtO 0 H3C 11 C 1. Br₂ PBr OH 2 H₂O 010 0 CH3CH₂OH C CH2 OEt Ha CH3CH2OH на NaCN H₂SO4 NC H₂O, heat CH2 OCH2CH3

Chapter 16 Solutions

EBK ORGANIC CHEMISTRY STUDY GUIDE AND S

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