(a) Interpretation: The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated. Concept introduction: Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane or aromatic compound.

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Answer 1

Question

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.

Answer 2

Question

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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Answer 3

Question

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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Answer 4

Question

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

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Answer 5

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

Answer 6

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Answer 7

Chapter 16, Problem 16.33P

Interpretation Introduction

(a)

Interpretation:

The synthesis of cylohexylcyclohexane from benzene and other reagents is to be stated.

Concept introduction:

Halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl halides or aromatic halides. This is known as the halogenation reaction. This is a free radical substitution reaction. In this, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane or aromatic compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butylcylcohexane from benzene and other reagents is to be stated.

Concept introduction:

The reaction between butyl chloride with benzene in presence of AlCl3 is a Friedel craft alkylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of alkyl group on benzene ring.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains how halogens react with alkanes or aromatic compounds in the presence of heat or light to form alkyl

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Chapter 16 Solutions