Organic Chemistry
Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
Question
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Chapter 16, Problem 16.1P
Interpretation Introduction

(a)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  1

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is a conjugated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  2

Figure 2

In the given diene, two double bonds are separated by a single bond. Thus, the given diene is a conjugated diene.

Conclusion

The given diene is a conjugated diene.

Interpretation Introduction

(b)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  3

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is an isolated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  4

Figure 3

In the given diene, two double bonds are separated by a two sigma bonds. Thus, the given diene is an isolated diene.

Conclusion

The given diene is an isolated diene.

Interpretation Introduction

(c)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  5

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is a conjugated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  6

Figure 4

In the given diene, two double bonds are separated by a single bond. Thus, the given diene is a conjugated diene.

Conclusion

The given diene is a conjugated diene.

Interpretation Introduction

(d)

Interpretation: The given diene is to be classified as isolated or conjugated.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated idene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  7

Figure 1

Expert Solution
Check Mark

Answer to Problem 16.1P

The given diene is an isolated diene.

Explanation of Solution

Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The given diene is shown below.

Organic Chemistry, Chapter 16, Problem 16.1P , additional homework tip  8

Figure 5

In the given diene, two double bonds are separated by more than single bond. Thus, the given diene is an isolated diene.

Conclusion

The given diene is an isolated diene.

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Chapter 16 Solutions

Organic Chemistry

Ch. 16 - Problem 16.11 Neuroprotectin D1 (NPD1) is...Ch. 16 - Problem 16.12 Using hybridization, predict how the...Ch. 16 - Problem 16.13 Use resonance theory to explain why...Ch. 16 - Prob. 16.14PCh. 16 - Prob. 16.15PCh. 16 - Problem 16.16 Draw the products formed when each...Ch. 16 - Problem 16.17 Draw a stepwise mechanism for the...Ch. 16 - Prob. 16.18PCh. 16 - Problem 16.19 Draw the product formed when each...Ch. 16 - Prob. 16.20PCh. 16 - Prob. 16.21PCh. 16 - Problem 16.22 Rank the following dienophiles in...Ch. 16 - Prob. 16.23PCh. 16 - Prob. 16.24PCh. 16 - Problem 16.25 What diene and dienophile are needed...Ch. 16 - Prob. 16.26PCh. 16 - Problem 16.27 Which compound in each pair absorbs...Ch. 16 - Prob. 16.28PCh. 16 - 16.29 Name each diene and state whether the...Ch. 16 - Prob. 16.30PCh. 16 - 16.31 Which of the following systems are...Ch. 16 - 16.32 Draw all reasonable resonance structures for...Ch. 16 - Prob. 16.33PCh. 16 - Prob. 16.34PCh. 16 - 16.35 Explain why the cyclopentadienide anion A...Ch. 16 - Prob. 16.36PCh. 16 - 16.37 Draw the structure of each compound. a. in...Ch. 16 - Prob. 16.38PCh. 16 - 16.39 Label each pair of compounds as...Ch. 16 - Prob. 16.40PCh. 16 - 16.41 Draw the products formed when each compound...Ch. 16 - Prob. 16.42PCh. 16 - 16.43 Treatment of alkenes A and B with gives the...Ch. 16 - 16.44 Draw a stepwise mechanism for the following...Ch. 16 - Prob. 16.45PCh. 16 - 16.46 Explain, with reference to the mechanism,...Ch. 16 - Prob. 16.47PCh. 16 - Prob. 16.48PCh. 16 - Prob. 16.49PCh. 16 - Prob. 16.50PCh. 16 - Prob. 16.51PCh. 16 - Prob. 16.52PCh. 16 - 16.53 Diels–Alder reaction of a monosubstituted...Ch. 16 - Prob. 16.54PCh. 16 - 16.55 Devise a stepwise synthesis of each compound...Ch. 16 - Prob. 16.56PCh. 16 - 16.57 A transannular Diels–Alder reaction is an...Ch. 16 - Prob. 16.58PCh. 16 - Draw a stepwise mechanism for the following...Ch. 16 - Prob. 16.60PCh. 16 - Prob. 16.61PCh. 16 - Prob. 16.62PCh. 16 - Prob. 16.63PCh. 16 - Prob. 16.64PCh. 16 - 16.65 The treatment of isoprene with one...Ch. 16 - 16.66 The treatment of with forms B (molecular...Ch. 16 - Prob. 16.67PCh. 16 - Prob. 16.68PCh. 16 - Prob. 16.69PCh. 16 - Prob. 16.70PCh. 16 - Prob. 16.71PCh. 16 - Prob. 16.72PCh. 16 - Prob. 16.73PCh. 16 - Prob. 16.74PCh. 16 - Prob. 16.75P
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