(a)
Interpretation:
To analyse whether the given statement: In the IUPAC system, primary aliphatic
Concept Introduction:
In ammonia when one among the three atoms of hydrogen is replaced by either an alkyl group or
(b)
Interpretation:
To analyse whether the given statement: The IUPAC name of
Concept Introduction:
The systematic method of naming the chemical compound in
(c)
Interpretation:
To analyse whether the given statement: 2-butanamine is chiral and shows enantiomerism, is true or not.
Concept Introduction:
Mirror images of chiral molecules that are not superimposable is known as enantiomers.
(d)
Interpretation:
To analyse whether the given statement: N,N-Dimethylaniline is a 3° aromatic amine, is true or not.
Concept Introduction:
The amine compound that has aromatic ring which is one of the compound classifications which has aniline encompassed is known as aromatic amines.
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Chapter 16 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
- 16-15 There are eight primary amines with the molecular formula C5H13N. (a) Name and draw a structural formula for each amine. (b > Which of these amines are chiral?arrow_forward16-13 Classify each amino group as primary, secondary, or tertiary and as aliphatic or aromatic. Serotonin (a neurotransmitter) Diphenhydramine (the hydrochloride salt is the antihistamine Benadryl) Lysine (an amino acid)arrow_forwardName this amine. H₂C—CH₂CH₂CH₂-CH-CH₂-CH₂ 1-methylpropan-1-amine NH₂ x 5arrow_forward
- True or False Amine salts have increased solubility in water. Amines have a pleasant floral aroma. Carboxylic acids have significantly higher boiling points than alcohols of comparable molecular weight Butanal would have a higher boiling point than butanoic acid. Pentanone would have a lower boiling point than pentane. Carboxylate ions have decreased solubility in water.arrow_forwardr Talking: Question 14.b of 25 Classify and describe the properties of the following nitrogen containing compound. Provide a systematic name for this structure. 2- N,N- 4- 1- tert- tri di sec- H N H. I N- N,N,N- n- prop but hex Submit +arrow_forward11. Write the chemical reaction for the acid hydrolysis of each amide sample. Include the 유 condensed structural formulas of the reactants and products. 11 CH3-C-NH₂ +H20+HCI CH3-C-OH + NH4+ CI- ACETAMIDE SO -NH2 +H20 T → 0 COOH + NH 3 11arrow_forward
- Amines with more than 6 carbons are soluble in: a) aqueous HCI b) aqueous NaHCO3 d) water c) aqueous NaOH Which of the following would give a positive iodoform test? acetone a) benzophenone c) 3-pentanone d) cyclopentanone meth "Saponification" as the term is used in organic chemistry means: a) acidic hydrolysis of an ester b) basic hydrolysis of an ester c) acidic hydrolysis of an amide d) basic hydrolysis of an amide 3. ( Propylamine can be synthesized by the LiAlH4 reduction of: a) CH3CH2CECH b) CH3CH=NH d)) CH3CH2CEN c) CH3CH2NO2arrow_forwardFalse True Amines react with strong acids such as HCI, to form ammonium salts Steroids are lipids that do not contain fatty acids Alkylamines have boiling points are higher than those of alkanes, but lower than those of alcohols The dipoles present in carboxylic acids allow these compounds toparticipate in hydrogen bonding with like molecules and water Amines are weak bases, they are considerably more basic than alcohols, and water In general, oils come from animal sources and fats from vegetable sources Secondary alcohols are readily oxidized with common oxidizing agents to carboxylic acids Carboxylic acids are less acidic than alcoholsarrow_forwardWhat is the correct assignment of the names of the functional groups in the following nitrogen-containing compounds? N(CH,)2 -NHCH3 CH,NH-NHCH, 1 2 3 A 1= 2° amine; 2 = enamine; 3 = hydrazine 1= 2° amine; 2 = amide; 3 = nitrile 1 = imine; 2 = hydrazone; 3 = amide 1=oxime; 2 = hydrazone; 3 = nitrilearrow_forward
- 17-50 Draw the structure of the amine salt produced when each of the following amines reacts with HCl. a. CH3-CH,-CH2-NH2 b. CH3-NH-CH3 CH3 c. CH,-CH-CH;-NH, d.[NH-CH;-Ch -NH-CH-CHarrow_forwardIn condensed structural formulas, the amide group in an amide produced from a carboxylic acid and a secondary amine can be written as -CO-NH-. Write the balanced chemical equation for the hydrolysis of N-ethylethanamide with NaOH. CH, CO-NH CH, CH3 + H2O + NAOH Heat CH3-COOH + Na NH,-CH2-CH3 CH3-CO-NH-CH CH3 + HO+ NaOH Heat → CH3-COO H3o'+ Na NH2-CH2-CH3 CH-CO-NH-CH-CH3 + NAOH Heat → CH CO Na + OHNH-CH2-CH3 Heat CH3-CO-NH-CH2-CH3 + NaOH CH3-COO Na" + NH2-CH2-CH3arrow_forwardFill-in the missing reagents and products for the synthesis of amines.arrow_forward
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