The mathematical relation between solubility product, K sp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 . Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

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Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

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Answer 3

Question

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

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Answer 4

Question

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

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Answer 5

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 6

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 7

Chapter 16, Problem 11Q

(i)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 8

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 9

(ii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 10

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 11

(iii)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 12

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 13

(iv)

Interpretation Introduction

Interpretation: The mathematical relation between solubility product, Ksp and molar solubility, s are given. The example of a salt for each mathematical representation is to be given with reference to Table 15-1 .

Concept introduction: At equilibrium, the measure of maximum amount of solute that is to be dissolved in a solvent is known as solubility. Solubility product is defined as the product of concentration of ions in a saturated solution where each ion is raised to the power of their coefficients.

Answer 14

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Solution Summary: The author explains the mathematical relation between solubility product, K_sp and molar

Chapter 16 Solutions