The entropy change for the formation of 1 mol of C 2 H 2 ( g ) from hydrogen and carbon under standard conditions has to be calculated. Concept Introduction: The term entropy is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less ordered arrangement, then the entropy of the system increases. The second law of thermodynamics state that “the entropy of the system either increases or remains the same.”
The entropy change for the formation of 1 mol of C 2 H 2 ( g ) from hydrogen and carbon under standard conditions has to be calculated. Concept Introduction: The term entropy is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less ordered arrangement, then the entropy of the system increases. The second law of thermodynamics state that “the entropy of the system either increases or remains the same.”
Solution Summary: The author explains that entropy is used to represent the randomness in a system.
Science that deals with the amount of energy transferred from one equilibrium state to another equilibrium state.
Chapter 16, Problem 113QRT
(a)
Interpretation Introduction
Interpretation:
The entropy change for the formation of 1mol of C2H2(g) from hydrogen and carbon under standard conditions has to be calculated.
Concept Introduction:
The term entropy is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less ordered arrangement, then the entropy of the system increases. The second law of thermodynamics state that “the entropy of the system either increases or remains the same.”
(b)
Interpretation Introduction
Interpretation:
The entropy change for the formation of 1mol of C2H4(g) from hydrogen and carbon under standard conditions has to be calculated.
Concept Introduction:
Refer to concept of part (a).
(c)
Interpretation Introduction
Interpretation:
The entropy change for the formation of 1mol of C2H6(g) from hydrogen and carbon under standard conditions has to be calculated. Whether the value of ΔrS° increases or decreases on adding more number of hydrogen atoms has to be stated.
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
Don't used Ai solution
In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 16 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY