The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring is to be drawn. The number of Ï€ electrons in indole is to be given. The electronic relationship of indole with that of naphthalene is to be stated. Concept introduction: The orbital picture of a compound shows the Ïƒ bonds in a molecule along with the unhybridized p orbitals on each atom in the ring containing the electrons involved in delocalization. To draw: The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring. To give: The number of Ï€ electrons in indole. To state: The electronic relationship of indole with that of naphthalene.

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Chapter 15.SE, Problem 37AP

Interpretation Introduction

Interpretation:

The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring is to be drawn.

The number of Ï€ electrons in indole is to be given.

The electronic relationship of indole with that of naphthalene is to be stated.

Concept introduction:

The orbital picture of a compound shows the Ïƒ bonds in a molecule along with the unhybridized p orbitals on each atom in the ring containing the electrons involved in delocalization.

To draw:

The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring.

To give:

The number of Ï€ electrons in indole.

To state:

The electronic relationship of indole with that of naphthalene.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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