Thermodynamics: An Engineering Approach
9th Edition
ISBN: 9781260048766
Author: CENGEL
Publisher: MCG
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Chapter 15.7, Problem 86P
What does the Gibbs function of formation
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Plot the following in a Gibbs Triangular System:
Point H: 35% A, 17%B, 48%C ; point A: 57%A, 18%B,
25% C ;point M: 4%A, 77%B, 19%C
The change in the molar volume accompanying fusion of solid benzene is 0.5 cm3 mol−1. Determine the change in Gibbs energy of fusion when the pressure is increased from 1 bar to 5000 bar.
3) An ideal gas consisting of one mole of molecules of type A is in contact with the
surroundings at T=300 K, and under a constant pressure of 1 atm. The gas undergoes a
spontaneous isomeric chemical reaction, wherein some fraction x of molecules of type A
change shape, become isomers of type B. This results in an equilibrium mixture of 1-x moles
of A and x moles of B. The enthalpy of B is lower than the enthalpy of A by 3 kJ/mole, such
that AH = -xɛ; & = 3kJ/mole . The change in entropy is given by
AS ==R(xln x+ (1–x)ln(1– x)).
Use the computer to graph the change in Gibbs free energy as a function of x. Determine, by
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when equilibrium is obtained. What is the maximum work that could be extracted from this
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P= latm (consternt)
T: 300k
Chapter 15 Solutions
Thermodynamics: An Engineering Approach
Ch. 15.7 - What are the approximate chemical compositions of...Ch. 15.7 - How does the presence of N2 in air affect the...Ch. 15.7 - Prob. 3PCh. 15.7 - Prob. 4PCh. 15.7 - Is the airfuel ratio expressed on a mole basis...Ch. 15.7 - How does the presence of moisture in air affect...Ch. 15.7 - Prob. 7PCh. 15.7 - Prob. 8PCh. 15.7 - Prob. 9PCh. 15.7 - Are complete combustion and theoretical combustion...
Ch. 15.7 - What does 100 percent theoretical air represent?Ch. 15.7 - Consider a fuel that is burned with (a) 130...Ch. 15.7 - What are the causes of incomplete combustion?Ch. 15.7 - Which is more likely to be found in the products...Ch. 15.7 - Methane (CH4) is burned with the stoichiometric...Ch. 15.7 - Prob. 16PCh. 15.7 - n-Butane fuel (C4H10) is burned with the...Ch. 15.7 - Prob. 18PCh. 15.7 - Propane (C3H8) is burned with 75 percent excess...Ch. 15.7 - Propane fuel (C3H8) is burned with 30 percent...Ch. 15.7 - In a combustion chamber, ethane (C2H6) is burned...Ch. 15.7 - Prob. 22PCh. 15.7 - Prob. 23PCh. 15.7 - Ethane (C2H6) is burned with 20 percent excess air...Ch. 15.7 - Octane (C8H18) is burned with 250 percent...Ch. 15.7 - Prob. 26PCh. 15.7 - A fuel mixture of 60 percent by mass methane (CH4)...Ch. 15.7 - Prob. 28PCh. 15.7 - A certain natural gas has the following volumetric...Ch. 15.7 - Prob. 30PCh. 15.7 - A gaseous fuel with a volumetric analysis of 45...Ch. 15.7 - Prob. 33PCh. 15.7 - The fuel mixer in a natural gas burner mixes...Ch. 15.7 - Prob. 35PCh. 15.7 - Prob. 36PCh. 15.7 - Determine the fuelair ratio when coal from...Ch. 15.7 - Prob. 38PCh. 15.7 - Prob. 39PCh. 15.7 - Prob. 40PCh. 15.7 - Prob. 41PCh. 15.7 - When are the enthalpy of formation and the...Ch. 15.7 - Prob. 43PCh. 15.7 - Prob. 44PCh. 15.7 - Prob. 45PCh. 15.7 - Prob. 46PCh. 15.7 - Prob. 48PCh. 15.7 - Repeat Prob. 1546 for liquid octane (C8H18).Ch. 15.7 - Ethane (C2H6) is burned at atmospheric pressure...Ch. 15.7 - Reconsider Prob. 1550. What minimum pressure of...Ch. 15.7 - Calculate the HHV and LHV of gaseous n-octane fuel...Ch. 15.7 - Prob. 53PCh. 15.7 - Consider a complete combustion process during...Ch. 15.7 - Prob. 56PCh. 15.7 - Prob. 57PCh. 15.7 - Prob. 58PCh. 15.7 - Propane fuel (C3H8) is burned with an airfuel...Ch. 15.7 - Prob. 60PCh. 15.7 - Prob. 61PCh. 15.7 - Prob. 62PCh. 15.7 - Octane gas (C8H18) at 25C is burned steadily with...Ch. 15.7 - Liquid ethyl alcohol [C2H5OH(l)] at 25C is burned...Ch. 15.7 - Prob. 66PCh. 15.7 - A gaseous fuel mixture that is 40 percent propane...Ch. 15.7 - A constant-volume tank contains a mixture of 120 g...Ch. 15.7 - Prob. 70PCh. 15.7 - Prob. 71PCh. 15.7 - Prob. 72PCh. 15.7 - A fuel is completely burned first with the...Ch. 15.7 - Prob. 74PCh. 15.7 - Prob. 75PCh. 15.7 - What is the adiabatic flame temperature of methane...Ch. 15.7 - Octane gas (C8H18) at 25C is burned steadily with...Ch. 15.7 - Acetylene gas (C2H2) at 25C is burned during a...Ch. 15.7 - Ethyl alcohol [C2H5OH(g)] is burned with 200...Ch. 15.7 - Prob. 81PCh. 15.7 - Prob. 82PCh. 15.7 - Reconsider Prob. 1582. The combustion products are...Ch. 15.7 - Express the increase of entropy principle for...Ch. 15.7 - Prob. 85PCh. 15.7 - What does the Gibbs function of formation gf of a...Ch. 15.7 - Liquid octane (C8H18) enters a steady-flow...Ch. 15.7 - Prob. 88PCh. 15.7 - Reconsider Prob. 1588. The automobile engine is to...Ch. 15.7 - Benzene gas (C6H6) at 1 atm and 77F is burned...Ch. 15.7 - Prob. 91PCh. 15.7 - n-Octane [C8H18(l)] is burned in the...Ch. 15.7 - A steady-flow combustion chamber is supplied with...Ch. 15.7 - Prob. 94RPCh. 15.7 - Prob. 95RPCh. 15.7 - Prob. 96RPCh. 15.7 - Prob. 97RPCh. 15.7 - Prob. 98RPCh. 15.7 - Prob. 99RPCh. 15.7 - n-Butane (C4H10) is burned with the stoichiometric...Ch. 15.7 - A gaseous fuel mixture of 60 percent propane...Ch. 15.7 - Calculate the higher and lower heating values of...Ch. 15.7 - Prob. 103RPCh. 15.7 - Methane gas (CH4) at 25C is burned steadily with...Ch. 15.7 - A 6-m3 rigid tank initially contains a mixture of...Ch. 15.7 - Propane gas (C3H8) enters a steady-flow combustion...Ch. 15.7 - Determine the highest possible temperature that...Ch. 15.7 - Liquid propane [C3H8(l)] enters a combustion...Ch. 15.7 - Prob. 109RPCh. 15.7 - Prob. 110RPCh. 15.7 - Prob. 111RPCh. 15.7 - A steam boiler heats liquid water at 200C to...Ch. 15.7 - Repeat Prob. 15112 using a coal from Utah that has...Ch. 15.7 - Liquid octane (C8H18) enters a steady-flow...Ch. 15.7 - Prob. 115RPCh. 15.7 - Consider the combustion of a mixture of an...Ch. 15.7 - Prob. 117RPCh. 15.7 - A fuel is burned steadily in a combustion chamber....Ch. 15.7 - A fuel is burned with 70 percent theoretical air....Ch. 15.7 - Prob. 126FEPCh. 15.7 - One kmol of methane (CH4) is burned with an...Ch. 15.7 - The higher heating value of a hydrocarbon fuel...Ch. 15.7 - Acetylene gas (C2H2) is burned completely during a...Ch. 15.7 - An equimolar mixture of carbon dioxide and water...Ch. 15.7 - A fuel is burned during a steady-flow combustion...
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