CENGEL'S 9TH EDITION OF THERMODYNAMICS:
9th Edition
ISBN: 9781260917055
Author: CENGEL
Publisher: MCG
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Chapter 15.7, Problem 85P
To determine
How are the absolute entropy values of ideal gases at pressures different from
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A mole sample of liquid ammonia at 273 Kelvin is cooled to liquid ammonia at 240 Kelvin. The process is done irreversibly by placing the sample in liquid nitrogen at 77 Kelvin. The heat capacity relationship for ammonia gas is given below. Assuming that the heat of vaporization is 23.4 KiloJoules per mole, answer the questions that follow.
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What is the total entropy change (or the entropy of the universe) for this process (in Joules per Kelvin)? Express answer in THREE SIGNIFICANT FIGURES.
Chapter 15 Solutions
CENGEL'S 9TH EDITION OF THERMODYNAMICS:
Ch. 15.7 - What are the approximate chemical compositions of...Ch. 15.7 - How does the presence of N2 in air affect the...Ch. 15.7 - Prob. 3PCh. 15.7 - Prob. 4PCh. 15.7 - Is the airfuel ratio expressed on a mole basis...Ch. 15.7 - How does the presence of moisture in air affect...Ch. 15.7 - Prob. 7PCh. 15.7 - Prob. 8PCh. 15.7 - Prob. 9PCh. 15.7 - Are complete combustion and theoretical combustion...
Ch. 15.7 - What does 100 percent theoretical air represent?Ch. 15.7 - Consider a fuel that is burned with (a) 130...Ch. 15.7 - What are the causes of incomplete combustion?Ch. 15.7 - Which is more likely to be found in the products...Ch. 15.7 - Methane (CH4) is burned with the stoichiometric...Ch. 15.7 - Prob. 16PCh. 15.7 - n-Butane fuel (C4H10) is burned with the...Ch. 15.7 - Prob. 18PCh. 15.7 - Propane (C3H8) is burned with 75 percent excess...Ch. 15.7 - Propane fuel (C3H8) is burned with 30 percent...Ch. 15.7 - In a combustion chamber, ethane (C2H6) is burned...Ch. 15.7 - Prob. 22PCh. 15.7 - Prob. 23PCh. 15.7 - Ethane (C2H6) is burned with 20 percent excess air...Ch. 15.7 - Octane (C8H18) is burned with 250 percent...Ch. 15.7 - Prob. 26PCh. 15.7 - A fuel mixture of 60 percent by mass methane (CH4)...Ch. 15.7 - Prob. 28PCh. 15.7 - A certain natural gas has the following volumetric...Ch. 15.7 - Prob. 30PCh. 15.7 - A gaseous fuel with a volumetric analysis of 45...Ch. 15.7 - Prob. 33PCh. 15.7 - The fuel mixer in a natural gas burner mixes...Ch. 15.7 - Prob. 35PCh. 15.7 - Prob. 36PCh. 15.7 - Determine the fuelair ratio when coal from...Ch. 15.7 - Prob. 38PCh. 15.7 - Prob. 39PCh. 15.7 - Prob. 40PCh. 15.7 - Prob. 41PCh. 15.7 - When are the enthalpy of formation and the...Ch. 15.7 - Prob. 43PCh. 15.7 - Prob. 44PCh. 15.7 - Prob. 45PCh. 15.7 - Prob. 46PCh. 15.7 - Prob. 48PCh. 15.7 - Repeat Prob. 1546 for liquid octane (C8H18).Ch. 15.7 - Ethane (C2H6) is burned at atmospheric pressure...Ch. 15.7 - Reconsider Prob. 1550. What minimum pressure of...Ch. 15.7 - Calculate the HHV and LHV of gaseous n-octane fuel...Ch. 15.7 - Prob. 53PCh. 15.7 - Consider a complete combustion process during...Ch. 15.7 - Prob. 56PCh. 15.7 - Prob. 57PCh. 15.7 - Prob. 58PCh. 15.7 - Propane fuel (C3H8) is burned with an airfuel...Ch. 15.7 - Prob. 60PCh. 15.7 - Prob. 61PCh. 15.7 - Prob. 62PCh. 15.7 - Octane gas (C8H18) at 25C is burned steadily with...Ch. 15.7 - Liquid ethyl alcohol [C2H5OH(l)] at 25C is burned...Ch. 15.7 - Prob. 66PCh. 15.7 - A gaseous fuel mixture that is 40 percent propane...Ch. 15.7 - A constant-volume tank contains a mixture of 120 g...Ch. 15.7 - Prob. 70PCh. 15.7 - Prob. 71PCh. 15.7 - Prob. 72PCh. 15.7 - A fuel is completely burned first with the...Ch. 15.7 - Prob. 74PCh. 15.7 - Prob. 75PCh. 15.7 - What is the adiabatic flame temperature of methane...Ch. 15.7 - Octane gas (C8H18) at 25C is burned steadily with...Ch. 15.7 - Acetylene gas (C2H2) at 25C is burned during a...Ch. 15.7 - Ethyl alcohol [C2H5OH(g)] is burned with 200...Ch. 15.7 - Prob. 81PCh. 15.7 - Prob. 82PCh. 15.7 - Reconsider Prob. 1582. The combustion products are...Ch. 15.7 - Express the increase of entropy principle for...Ch. 15.7 - Prob. 85PCh. 15.7 - What does the Gibbs function of formation gf of a...Ch. 15.7 - Liquid octane (C8H18) enters a steady-flow...Ch. 15.7 - Prob. 88PCh. 15.7 - Reconsider Prob. 1588. The automobile engine is to...Ch. 15.7 - Benzene gas (C6H6) at 1 atm and 77F is burned...Ch. 15.7 - Prob. 91PCh. 15.7 - n-Octane [C8H18(l)] is burned in the...Ch. 15.7 - A steady-flow combustion chamber is supplied with...Ch. 15.7 - Prob. 94RPCh. 15.7 - Prob. 95RPCh. 15.7 - Prob. 96RPCh. 15.7 - Prob. 97RPCh. 15.7 - Prob. 98RPCh. 15.7 - Prob. 99RPCh. 15.7 - n-Butane (C4H10) is burned with the stoichiometric...Ch. 15.7 - A gaseous fuel mixture of 60 percent propane...Ch. 15.7 - Calculate the higher and lower heating values of...Ch. 15.7 - Prob. 103RPCh. 15.7 - Methane gas (CH4) at 25C is burned steadily with...Ch. 15.7 - A 6-m3 rigid tank initially contains a mixture of...Ch. 15.7 - Propane gas (C3H8) enters a steady-flow combustion...Ch. 15.7 - Determine the highest possible temperature that...Ch. 15.7 - Liquid propane [C3H8(l)] enters a combustion...Ch. 15.7 - Prob. 109RPCh. 15.7 - Prob. 110RPCh. 15.7 - Prob. 111RPCh. 15.7 - A steam boiler heats liquid water at 200C to...Ch. 15.7 - Repeat Prob. 15112 using a coal from Utah that has...Ch. 15.7 - Liquid octane (C8H18) enters a steady-flow...Ch. 15.7 - Prob. 115RPCh. 15.7 - Consider the combustion of a mixture of an...Ch. 15.7 - Prob. 117RPCh. 15.7 - A fuel is burned steadily in a combustion chamber....Ch. 15.7 - A fuel is burned with 70 percent theoretical air....Ch. 15.7 - Prob. 126FEPCh. 15.7 - One kmol of methane (CH4) is burned with an...Ch. 15.7 - The higher heating value of a hydrocarbon fuel...Ch. 15.7 - Acetylene gas (C2H2) is burned completely during a...Ch. 15.7 - An equimolar mixture of carbon dioxide and water...Ch. 15.7 - A fuel is burned during a steady-flow combustion...
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- Express the Joule coefficient and the Joule – Thomson coefficient as its value for an ideal gas.arrow_forward(a) In reaching equilibrium, how much heat transfer occurs from 1.00 kg of water at 40.0º C when it is placed in contact with 1.00 kg of 20.0º C water in reaching equilibrium? (b) What is the change in entropy due to this heat transfer? (c) How much work is made unavailable, taking the lowest temperature to be 20.0º C ? Explicitly show how you follow the steps in the Problem-Solving Strategies for Entropy.arrow_forwardCalculate the molar entropy change (cal/mol-K) for the irreversible vaporization of superheated liquid water at 102 °C. = 9.7 kcal/mol, vap- C P, liquid water = 18 cal/mol-K Cp P, steam (cal/mol-K) = 7.2 + 2.4 x 10-3Tarrow_forward
- Calculate the entropy changes of the system and surrounding for the case of isothermal freezing of one mole of supercooled liquid silver at 804°C, when the surrounding are also at the same temperature.arrow_forwardUsing the Clapeyron equation, determine the latent heat of vaporization of saturated Propane. Data: Temperature: 40°F; Pressure: 77.80 psia; Liquid volume: 0.03055 ft3/lbm; Vapor volume: 1.33 ft3/lbm.arrow_forwardRefrigerant 134a (R134a) is in vapor/liquid equilibrium at 200 K. The saturation pressure is 7.0282 bar, the enthalpy of the saturated liquid is 107.39 kJ/kg and the enthalpy of the saturated vapor is 353.06 kJ/kg. Compute the entropy of vaporization in units of kJ/(kg K). Report your answer using three decimal placesarrow_forward
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What is entropy? - Jeff Phillips; Author: TED-Ed;https://www.youtube.com/watch?v=YM-uykVfq_E;License: Standard youtube license