Basic Chemistry (5th Edition)
5th Edition
ISBN: 9780134138046
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 15.2, Problem 15.25QAP
Use the halt-reaction method to balance each of the following in basic solution
a.
b.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 15 Solutions
Basic Chemistry (5th Edition)
Ch. 15.1 - Prob. 15.1QAPCh. 15.1 - Prob. 15.2QAPCh. 15.1 - Prob. 15.3QAPCh. 15.1 - Prob. 15.4QAPCh. 15.1 - Prob. 15.5QAPCh. 15.1 - Prob. 15.6QAPCh. 15.1 - Prob. 15.7QAPCh. 15.1 - Prob. 15.8QAPCh. 15.1 - Prob. 15.9QAPCh. 15.1 - Prob. 15.10QAP
Ch. 15.1 - Prob. 15.11QAPCh. 15.1 - Prob. 15.12QAPCh. 15.1 - Prob. 15.13QAPCh. 15.1 - Prob. 15.14QAPCh. 15.1 - Prob. 15.15QAPCh. 15.1 - Prob. 15.16QAPCh. 15.1 - Prob. 15.17QAPCh. 15.1 - Prob. 15.18QAPCh. 15.1 - Prob. 15.19QAPCh. 15.1 - Prob. 15.20QAPCh. 15.2 - Prob. 15.21QAPCh. 15.2 - Prob. 15.22QAPCh. 15.2 - Use the half-reaction method to balance each of...Ch. 15.2 - Prob. 15.24QAPCh. 15.2 - Use the halt-reaction method to balance each of...Ch. 15.2 - Prob. 15.26QAPCh. 15.3 - Prob. 15.27QAPCh. 15.3 - Prob. 15.28QAPCh. 15.3 - Prob. 15.29QAPCh. 15.3 - Prob. 15.30QAPCh. 15.3 - Prob. 15.31QAPCh. 15.3 - Prob. 15.32QAPCh. 15.3 - Prob. 15.33QAPCh. 15.3 - Prob. 15.34QAPCh. 15.3 - Prob. 15.35QAPCh. 15.3 - Prob. 15.36QAPCh. 15.4 - Prob. 15.37QAPCh. 15.4 - Prob. 15.38QAPCh. 15.4 - Prob. 15.39QAPCh. 15.4 - Prob. 15.40QAPCh. 15 - Prob. 15.41FUCh. 15 - Prob. 15.42FUCh. 15 - Prob. 15.43UTCCh. 15 - Prob. 15.44UTCCh. 15 - Prob. 15.45UTCCh. 15 - Prob. 15.46UTCCh. 15 - Prob. 15.47UTCCh. 15 - Prob. 15.48UTCCh. 15 - Prob. 15.49AUTCCh. 15 - Prob. 15.50AUTCCh. 15 - Prob. 15.51AUTCCh. 15 - Prob. 15.52AUTCCh. 15 - Prob. 15.53AUTCCh. 15 - Prob. 15.54AUTCCh. 15 - Which of the following are notation-reduction...Ch. 15 - Prob. 15.56AQAPCh. 15 - Prob. 15.57AQAPCh. 15 - Prob. 15.58AQAPCh. 15 - 15.59 Assign oxidation numbers to all the elements...Ch. 15 - Prob. 15.60AQAPCh. 15 - Assign oxidation numbers to all the elements in...Ch. 15 - Assign oxidation numbers to all the elements in...Ch. 15 - Prob. 15.63AQAPCh. 15 - Prob. 15.64AQAPCh. 15 - 15.65 Use the activity series in Table 15.3 to...Ch. 15 - Prob. 15.66AQAPCh. 15 - Prob. 15.67AQAPCh. 15 - In a voltaic cell, one half-cell consists of zinc...Ch. 15 - Prob. 15.69AQAPCh. 15 - 15.70 Use the activity series in Table 15.3 to...Ch. 15 - 15.71 In a lead storage battery. the following...Ch. 15 - Prob. 15.72AQAPCh. 15 - Prob. 15.73AQAPCh. 15 - Prob. 15.74AQAPCh. 15 - Prob. 15.75CQCh. 15 - Prob. 15.76CQCh. 15 - Prob. 15.77CQCh. 15 - Prob. 15.78CQCh. 15 - Prob. 15.79CQCh. 15 - Prob. 15.80CQCh. 15 - Prob. 15.81CQCh. 15 - The following unbalanced reaction takes place in...Ch. 15 - Prob. 15.83CQCh. 15 - Prob. 15.84CQCh. 15 - Using the activity series in Table 15.3, indicate...Ch. 15 - Using the activity series in Table 15.3, indicate...Ch. 15 - Prob. 15.87CQCh. 15 - Prob. 15.88CQ
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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