
(a)
Interpretation:
The number of moles of the indicated ion present in the given solution is to be calculated.
Concept Introduction:
The
The number of moles is calculated by the formula,
Moles=Mass(g)Molar mass
The molarity is calculated by the formula,
Molarity=Number of moles of soluteVolume of solution(in Liters).

Answer to Problem 49QAP
The number of moles of Na+ ions in solution is 0.502 moles.
Explanation of Solution
The volume and molarity of Na2SO4 solution is given to be 1.00 L and 0.251 M respectively.
The number of moles of a solute is calculated by the formula,
Number of moles of solute=Volume of solution×Molarity
Substitute the values of volume of solution and molarity of Na2SO4 solution in the above expression.
Number of moles of solute=1.00 L×0.251 M=0.251 moles
The solution of Na2SO4 consists of Na+ and SO2−4 ions. The compound Na2SO4 has two Na+ ions.
The number of moles of Na+ is calculated as shown below.
Moles of Na+=2×0.251 moles=0.502 moles
Therefore, the number of moles of Na+ ions in solution is 0.502 moles.
(b)
Interpretation:
The number of moles of the indicated ion present in the given solution is to be calculated.
Concept Introduction:
The atomic mass of an element is defined as the sum of number of protons and number of neutrons. Molar mass of an element is determined from atomic mass of an element.
The number of moles is calculated by the formula,
Moles=Mass(g)Molar mass
The molarity is calculated by the formula,
Molarity=Number of moles of soluteVolume of solution(in Liters).

Answer to Problem 49QAP
The number of moles of Cl− ions in solution is 1.65 moles.
Explanation of Solution
The volume and molarity of FeCl3 solution is given to be 5.50 L and 0.10 M respectively.
The number of moles of a solute is calculated by the formula,
Number of moles of solute=Volume of solution×Molarity
Substitute the values of volume of solution and molarity of FeCl3 solution in the above expression.
Number of moles of solute=5.50 L×0.10 M=0.55 moles
The solution of FeCl3 consists of Fe3+ and Cl− ions. The compound FeCl3 has three Cl− ions.
Thus, the number of moles of Cl− is calculated as shown below.
Moles of Cl−=3×0.55 moles=1.65 moles
Therefore, the number of moles of Cl− ions in solution is 1.65 moles.
(c)
Interpretation:
The number of moles of the indicated ion present in the given solution is to be calculated.
Concept Introduction:
The atomic mass of an element is defined as the sum of number of protons and number of neutrons. Molar mass of an element is determined from atomic mass of an element.
The number of moles is calculated by the formula,
Moles=Mass(g)Molar mass
The molarity is calculated by the formula,
Molarity=Number of moles of soluteVolume of solution(in Liters).

Answer to Problem 49QAP
The number of moles of NO−3 ions in solution is 0.11 moles.
Explanation of Solution
The volume and molarity of Ba(NO3)2 solution is given to be 100 mL and 0.55 M respectively.
The conversion of units of volume into L is done as,
100 mL=1001000 L=0.1 L
The number of moles of a solute is calculated by the formula,
Number of moles of solute=Volume of solution×Molarity
Substitute the values of volume of solution and molarity of Ba(NO3)2 solution in the above expression.
Number of moles of solute=0.1 L×0.55 M=0.055 moles
The solution of Ba(NO3)2 consists of Ba2+ and NO−3 ions. The compound Ba(NO3)2 has two NO−3 ions.
Thus, the number of moles of NO−3 is calculated as shown below.
Moles of NO−3=2×0.055 moles=0.11 moles
Therefore, the number of moles of NO−3 ions in solution is 0.11 moles.
(d)
Interpretation:
The number of moles of the indicated ion present in the given solution is to be calculated.
Concept Introduction:
The atomic mass of an element is defined as the sum of number of protons and number of neutrons. Molar mass of an element is determined from atomic mass of an element.
The number of moles is calculated by the formula,
Moles=Mass(g)Molar mass
The molarity is calculated by the formula,
Molarity=Number of moles of soluteVolume of solution(in Liters).

Answer to Problem 49QAP
The number of moles of NH+4 ions in solution is 0.175 moles.
Explanation of Solution
The volume and molarity of (NH4)2SO4 solution is given to be 250 mL and 0.350 M respectively.
The conversion of units of volume into L is done as,
250 mL=2501000 L=0.250 L
The number of moles of a solute is calculated by the formula,
Number of moles of solute=Volume of solution×Molarity
Substitute the values of volume of solution and molarity of (NH4)2SO4 solution in the above expression.
Number of moles of solute=0.250 L×0.350 M=0.0875 moles
The solution of (NH4)2SO4 consists of NH+4 and SO2−4 ions. The compound (NH4)2SO4 has two NH+4 ions.
Thus, the number of moles of NH+4 is calculated as shown below.
Moles of NH+4=2×0.0875 moles=0.175 moles
Therefore, the number of moles of NH+4 ions in solution is 0.175 moles.
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Chapter 15 Solutions
Introductory Chemistry: A Foundation
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