FOUND.OF COLLEGE CHEMISTRY
FOUND.OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781119234555
Author: Hein
Publisher: WILEY
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Chapter 15, Problem 44PE

(a)

Interpretation Introduction

Interpretation:

Out of the four classes amongst strong and weak acid, strong base, or weak base, class of (COOH)2 has to be identified and equation when (COOH)2 is dissolved in water has to be identified.

Concept Introduction:

An electrolyte refers to an ionic compound that on solvation in polar protic solvents ionizes to yield cationic and anionic species. The free movement of such ionic species results in the conduction of electricity.

Three subcategories exist for electrolyte namely strong electrolyte, weak electrolyte and non-electrolyte. The strong electrolytes on dissolution exhibit 100 % dissociation; in contrast, the weak electrolytes are not 100 % dissociated. However, the non-electrolytes barely dissociate or do not dissociate at all.

(b)

Interpretation Introduction

Interpretation:

Out of the four classes amongst strong acid, weak acid, strong base, or weak base, class of Ba(OH)2 has to be identified and equation when Ba(OH)2 is dissolved in water has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Out of the four classes amongst strong acid, weak acid, strong base, or weak base, class of HClO4 has to be identified and equation when HClO4 is dissolved in water should be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Out of the four classes amongst strong acid, weak acid, strong base, or weak base, class of HBr has to be identified and equation when HBr is dissolved in water has to be identified.

Concept Introduction:

Refer to part (a).

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(a) A 50.0 mL solution is prepared to be 1.29 M acetylsalicylic acid. In the first step, 8.55 mL of NaOH is titrated into the solution until the pH is exactly 5.0. What is the concentration of the titrant (NaOH)? (b) In the second step, enough 5.85 M nitric acid is added to the solution after the titration in part (a) is complete until the pH is one unit lower than the pKa of acetylsalicylic acid. What volume (mL) of nitric acid was added?
Determine the molar concentration of each ion present in the solutions that result from each of the following mixtures: (Disregard the concentration of H+ and OH- from water and assume that volumes are additive.) (a) 57.4 mL of 0.79 M HCl and 77.3 mL of 1.48 M HCl: (b) 120 mL of 0.59 M CaCl2 and 120 mL of 0.27 M CaCl2   (c) 31.9 mL of 0.369 M NaOH and 20.2 mL of 0.278 M HCl (d) 14.0 mL of 0.724 M H2SO4 and 20.3 mL of 0.110 M NaOH
A buffer solution was made by mixing 2.00 L of 1.500 M potassium nitrite with 1.00 L of 1.476 M nitrous acid. Ka (nitrous acid) = 4.5 x 10-4 For all to the following questions, write your answer as a normal number to three significant figures. (a) The molarity of the conjugate base in the solution at the instant of mixing is (b) The molarity of the weak acid in the solution at the instant of mixing is (c) The pH of the buffer after the mixing of the two solutions is Use the rules applicable to significant figures. (d) 19.04 g NaOH (39.9971 g/mol) is dissolved in this buffer solution (assume this causes no change in the volume of the solution) and reacts. The mole of added base remaining after the reaction is (e) At the same time, the moles of weak acid remaining is (f) At the same time, the moles of the conjugate base remaining is (9) THe pH of the buffer solution after the added base has reacted, is Use the rules applicable to significant figures.

Chapter 15 Solutions

FOUND.OF COLLEGE CHEMISTRY

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