EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Chapter 15, Problem 32CR
When calcium carbonate is heated strongly, it evolves carbon dioxide gas.
25 g of CaCO3 is heated, what mass of CO2would be produced? What volume would this quantity of CO2 (CU at STP?
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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Chapter 15 Solutions
EBK INTRODUCTORY CHEMISTRY
Ch. 15.3 - ercise 15.1 A 1 35-g sample of seawater is...Ch. 15.3 - Prob. 15.2SCCh. 15.4 - ercise 15.3 Calculate the molarity of a solution...Ch. 15.4 - ercise 15.4 Give the concentrations of the ions in...Ch. 15.4 - ercise 15.5 Calculate the number of moles of Cl...Ch. 15.4 - ercise 15.6 Formalin is an aqueous solution of...Ch. 15.5 - ercise 15.7 What volume of 12 M HCI must be taken...Ch. 15.6 - at if all ionic solids were soluble in water? How...Ch. 15.6 - Exercise 15.8 When aqueous solutions of Na2SO3 and...Ch. 15.7 - ercise 15.9 Calculate the volume of 0.10 M HNO3...
Ch. 15.8 - ercise 15.10 Calculate the normality of a solution...Ch. 15.8 - Prob. 15.11SCCh. 15 - ou have a solution of table sail in water. What...Ch. 15 - onsider a sugar solution (solution A) with...Ch. 15 - You need to make 150.0 mL of a 0.10 M NaCI...Ch. 15 - ou have two solutions containing solute A. To...Ch. 15 - m>5. Which of the following do you need to know to...Ch. 15 - onsider separate aqueous solutions of HCI and...Ch. 15 - Prob. 7ALQCh. 15 - an one solution have a greater concentration than...Ch. 15 - Prob. 9ALQCh. 15 - You have equal masses of different solutes...Ch. 15 - Which of the following solutions contains the...Ch. 15 - As with all quantitative problems in chemistry,...Ch. 15 - Prob. 13ALQCh. 15 - Prob. 14ALQCh. 15 - solution is a homogeneous mixture. Can you give an...Ch. 15 - ow do the properties of a nonhomogeneous...Ch. 15 - Prob. 3QAPCh. 15 - Prob. 4QAPCh. 15 - n Chapter 14. you learned that the bonding forces...Ch. 15 - n oil spill spreads out on the surface of water,...Ch. 15 - . The “Chemistry in Focus” segment Water, Water...Ch. 15 - Prob. 8QAPCh. 15 - Prob. 9QAPCh. 15 - Prob. 10QAPCh. 15 - A solution is a homogeneous mixture and, unlike a...Ch. 15 - Prob. 12QAPCh. 15 - How do we define the mass percent composition of a...Ch. 15 - Prob. 14QAPCh. 15 - Calculate the percent by mass of solute in each of...Ch. 15 - Calculate the percent by mass of solute in each of...Ch. 15 - Prob. 17QAPCh. 15 - Prob. 18QAPCh. 15 - A sample of an iron alloy contains 92.1 g Fe. 2.59...Ch. 15 - Consider the iron alloy described in Question 19....Ch. 15 - An aqueous solution is to be prepared that will be...Ch. 15 - Prob. 22QAPCh. 15 - A solution is to be prepared that will be 4.50% by...Ch. 15 - Prob. 24QAPCh. 15 - Prob. 25QAPCh. 15 - Hydrogen peroxide solutions sold in drugstores as...Ch. 15 - Prob. 27QAPCh. 15 - A solvent sold for use in the laboratory contains...Ch. 15 - Prob. 29QAPCh. 15 - Prob. 30QAPCh. 15 - What is a standard solution? Describe the steps...Ch. 15 - Prob. 32QAPCh. 15 - 33. For each of the following solutions, the...Ch. 15 - 34. For each of the following solutions, the...Ch. 15 - 35. For each of the following solutions, the mass...Ch. 15 - Prob. 36QAPCh. 15 - 37. A laboratory assistant needs to prepare 225 mL...Ch. 15 - Prob. 38QAPCh. 15 - 39. Standard solutions of calcium ion used to test...Ch. 15 - Prob. 40QAPCh. 15 - 41. If 42.5 g of NaOH is dissolved in water and...Ch. 15 - 42. Standard silver nitrate solutions are used in...Ch. 15 - Prob. 43QAPCh. 15 - Prob. 44QAPCh. 15 - Prob. 45QAPCh. 15 - Prob. 46QAPCh. 15 - Prob. 47QAPCh. 15 - 48. What mass of solute is present in 225 mL of...Ch. 15 - Prob. 49QAPCh. 15 - Prob. 50QAPCh. 15 - Prob. 51QAPCh. 15 - Strong acid solutions may have their concentration...Ch. 15 - Prob. 53QAPCh. 15 - Prob. 54QAPCh. 15 - Prob. 55QAPCh. 15 - Prob. 56QAPCh. 15 - Prob. 57QAPCh. 15 - Prob. 58QAPCh. 15 - Prob. 59QAPCh. 15 - 60. Suppose 325 in L of 0.150 M NaOH is needed for...Ch. 15 - 61. How much water must be added w 500. mL of...Ch. 15 - An experiment calls for 100. mL of 1.25 M HC1. All...Ch. 15 - Prob. 63QAPCh. 15 - 64. Generally only the carbonates of the Group I...Ch. 15 - 65. Many metal ions are precipitated from solution...Ch. 15 - 66. Calcium oxalate, CaCO4, is very insoluble in...Ch. 15 - 67. When aqueous solutions of lead(II) ion are...Ch. 15 - 68. Aluminum ion may be precipitated from aqueous...Ch. 15 - 69. What volume of 0.502 M NaOH solution would be...Ch. 15 - 70. What volume of a 0.500 M NaOH solution would...Ch. 15 - 71. A sample of sodium hydrogen carbonate solid...Ch. 15 - 72. The total acidity in water samples can be...Ch. 15 - Prob. 73QAPCh. 15 - Prob. 74QAPCh. 15 - Prob. 75QAPCh. 15 - Prob. 76QAPCh. 15 - 77. Explain why the equivalent weight of H2SO4 is...Ch. 15 - Prob. 78QAPCh. 15 - Prob. 79QAPCh. 15 - Prob. 80QAPCh. 15 - Prob. 81QAPCh. 15 - Prob. 82QAPCh. 15 - Prob. 83QAPCh. 15 - Prob. 84QAPCh. 15 - 85. How many milliliters of 0.50 N NaOH are...Ch. 15 - 86. What volume of 0.104 N H2SO4is required to...Ch. 15 - 87. What volume of 0.151 N NaOH is required to...Ch. 15 - Prob. 88QAPCh. 15 - 89. A mixture is prepared by mixing 50.0 g of...Ch. 15 - Prob. 90APCh. 15 - 91. Suppose 50.0 mL of 0.250 M CoCl2 solution is...Ch. 15 - Prob. 92APCh. 15 - 93. Calculate the mass of AgCl formed, and the...Ch. 15 - 94. Baking soda (sodium hydrogen carbonate....Ch. 15 - 95. Many metal ions form insoluble sulfide...Ch. 15 - Prob. 96APCh. 15 - Prob. 97APCh. 15 - Prob. 98APCh. 15 - Prob. 99APCh. 15 - Prob. 100APCh. 15 - Prob. 101APCh. 15 - You mix 225.0 mL of a 2.5 M HCl solution with...Ch. 15 - A solution is 0.1% by mass calcium chloride....Ch. 15 - Prob. 104APCh. 15 - Prob. 105APCh. 15 - A certain grade of steel is made by dissolving 5.0...Ch. 15 - Prob. 107APCh. 15 - Prob. 108APCh. 15 - Prob. 109APCh. 15 - Prob. 110APCh. 15 - How many moles of each ion are present in 11.7 mL...Ch. 15 - Prob. 112APCh. 15 - Prob. 113APCh. 15 - Prob. 114APCh. 15 - Concentrated hydrochloric acid is made by pumping...Ch. 15 - A large beaker contains 1.50 L of a 2.00 M...Ch. 15 - Prob. 117APCh. 15 - Prob. 118APCh. 15 - If 10. g of AgNO3 is available, what volume of...Ch. 15 - Prob. 120APCh. 15 - Calcium carbonate, CaCO3, can be obtained in a...Ch. 15 - Prob. 122APCh. 15 - How many milliliters of 18.0 M H2SO4 are required...Ch. 15 - Prob. 124APCh. 15 - When 10. L of water is added to 3.0 L of 6.0 M...Ch. 15 - You pour 150.0 mL of a 0.250 M lead(ll) nitrate...Ch. 15 - How many grams of Ba (NO3)2are required to...Ch. 15 - Prob. 128APCh. 15 - What volume of 0.250 M HCI is required to...Ch. 15 - Prob. 130APCh. 15 - Prob. 131APCh. 15 - Prob. 132APCh. 15 - How many milliliters of 0.105 M NaOH are required...Ch. 15 - Prob. 134APCh. 15 - Prob. 135APCh. 15 - Prob. 136APCh. 15 - Prob. 137CPCh. 15 - A solution is prepared by dissolving 0.6706 g of...Ch. 15 - What volume of 0.100 M NaOH is required to...Ch. 15 - Prob. 140CPCh. 15 - A 450.O-mL sample of a 0.257 M solution of silver...Ch. 15 - A 50.00-mL sample of aqueous Ca(OH)2 requires...Ch. 15 - When organic compounds containing sulfur are...Ch. 15 - Prob. 1CRCh. 15 - Prob. 2CRCh. 15 - Prob. 3CRCh. 15 - Prob. 4CRCh. 15 - Prob. 5CRCh. 15 - Prob. 6CRCh. 15 - Prob. 7CRCh. 15 - Prob. 8CRCh. 15 - Prob. 9CRCh. 15 - Prob. 10CRCh. 15 - Prob. 11CRCh. 15 - Without consulting your textbook, list and explain...Ch. 15 - What does “STP’ stand for? What conditions...Ch. 15 - Prob. 14CRCh. 15 - Prob. 15CRCh. 15 - Define the normal boiling point of water. Why does...Ch. 15 - Are changes in state physical or chemical changes?...Ch. 15 - Prob. 18CRCh. 15 - Prob. 19CRCh. 15 - Prob. 20CRCh. 15 - Define a crystalline solid. Describe in detail...Ch. 15 - Define the bonding that exists in metals and how...Ch. 15 - Prob. 23CRCh. 15 - Define a saturated solution. Does saturated mean...Ch. 15 - Prob. 25CRCh. 15 - When a solution is diluted by adding additional...Ch. 15 - Prob. 27CRCh. 15 - Prob. 28CRCh. 15 - Prob. 29CRCh. 15 - Prob. 30CRCh. 15 - Prob. 31CRCh. 15 - When calcium carbonate is heated strongly, it...Ch. 15 - If an electric current is passed through molten...Ch. 15 - Prob. 34CRCh. 15 - Prob. 35CRCh. 15 - Prob. 36CRCh. 15 - Prob. 37CRCh. 15 - Prob. 38CR
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