EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Textbook Question
Chapter 15.3, Problem 15.1SC
ercise 15.1 A 1 35-g sample of seawater is evaporated to dryness, leaving 4.73 g of solid residue (the salts formerly dissolved in the seawater). Calculate the mass percent of solute present in the original seawater.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 15 Solutions
EBK INTRODUCTORY CHEMISTRY
Ch. 15.3 - ercise 15.1 A 1 35-g sample of seawater is...Ch. 15.3 - Prob. 15.2SCCh. 15.4 - ercise 15.3 Calculate the molarity of a solution...Ch. 15.4 - ercise 15.4 Give the concentrations of the ions in...Ch. 15.4 - ercise 15.5 Calculate the number of moles of Cl...Ch. 15.4 - ercise 15.6 Formalin is an aqueous solution of...Ch. 15.5 - ercise 15.7 What volume of 12 M HCI must be taken...Ch. 15.6 - at if all ionic solids were soluble in water? How...Ch. 15.6 - Exercise 15.8 When aqueous solutions of Na2SO3 and...Ch. 15.7 - ercise 15.9 Calculate the volume of 0.10 M HNO3...
Ch. 15.8 - ercise 15.10 Calculate the normality of a solution...Ch. 15.8 - Prob. 15.11SCCh. 15 - ou have a solution of table sail in water. What...Ch. 15 - onsider a sugar solution (solution A) with...Ch. 15 - You need to make 150.0 mL of a 0.10 M NaCI...Ch. 15 - ou have two solutions containing solute A. To...Ch. 15 - m>5. Which of the following do you need to know to...Ch. 15 - onsider separate aqueous solutions of HCI and...Ch. 15 - Prob. 7ALQCh. 15 - an one solution have a greater concentration than...Ch. 15 - Prob. 9ALQCh. 15 - You have equal masses of different solutes...Ch. 15 - Which of the following solutions contains the...Ch. 15 - As with all quantitative problems in chemistry,...Ch. 15 - Prob. 13ALQCh. 15 - Prob. 14ALQCh. 15 - solution is a homogeneous mixture. Can you give an...Ch. 15 - ow do the properties of a nonhomogeneous...Ch. 15 - Prob. 3QAPCh. 15 - Prob. 4QAPCh. 15 - n Chapter 14. you learned that the bonding forces...Ch. 15 - n oil spill spreads out on the surface of water,...Ch. 15 - . The “Chemistry in Focus” segment Water, Water...Ch. 15 - Prob. 8QAPCh. 15 - Prob. 9QAPCh. 15 - Prob. 10QAPCh. 15 - A solution is a homogeneous mixture and, unlike a...Ch. 15 - Prob. 12QAPCh. 15 - How do we define the mass percent composition of a...Ch. 15 - Prob. 14QAPCh. 15 - Calculate the percent by mass of solute in each of...Ch. 15 - Calculate the percent by mass of solute in each of...Ch. 15 - Prob. 17QAPCh. 15 - Prob. 18QAPCh. 15 - A sample of an iron alloy contains 92.1 g Fe. 2.59...Ch. 15 - Consider the iron alloy described in Question 19....Ch. 15 - An aqueous solution is to be prepared that will be...Ch. 15 - Prob. 22QAPCh. 15 - A solution is to be prepared that will be 4.50% by...Ch. 15 - Prob. 24QAPCh. 15 - Prob. 25QAPCh. 15 - Hydrogen peroxide solutions sold in drugstores as...Ch. 15 - Prob. 27QAPCh. 15 - A solvent sold for use in the laboratory contains...Ch. 15 - Prob. 29QAPCh. 15 - Prob. 30QAPCh. 15 - What is a standard solution? Describe the steps...Ch. 15 - Prob. 32QAPCh. 15 - 33. For each of the following solutions, the...Ch. 15 - 34. For each of the following solutions, the...Ch. 15 - 35. For each of the following solutions, the mass...Ch. 15 - Prob. 36QAPCh. 15 - 37. A laboratory assistant needs to prepare 225 mL...Ch. 15 - Prob. 38QAPCh. 15 - 39. Standard solutions of calcium ion used to test...Ch. 15 - Prob. 40QAPCh. 15 - 41. If 42.5 g of NaOH is dissolved in water and...Ch. 15 - 42. Standard silver nitrate solutions are used in...Ch. 15 - Prob. 43QAPCh. 15 - Prob. 44QAPCh. 15 - Prob. 45QAPCh. 15 - Prob. 46QAPCh. 15 - Prob. 47QAPCh. 15 - 48. What mass of solute is present in 225 mL of...Ch. 15 - Prob. 49QAPCh. 15 - Prob. 50QAPCh. 15 - Prob. 51QAPCh. 15 - Strong acid solutions may have their concentration...Ch. 15 - Prob. 53QAPCh. 15 - Prob. 54QAPCh. 15 - Prob. 55QAPCh. 15 - Prob. 56QAPCh. 15 - Prob. 57QAPCh. 15 - Prob. 58QAPCh. 15 - Prob. 59QAPCh. 15 - 60. Suppose 325 in L of 0.150 M NaOH is needed for...Ch. 15 - 61. How much water must be added w 500. mL of...Ch. 15 - An experiment calls for 100. mL of 1.25 M HC1. All...Ch. 15 - Prob. 63QAPCh. 15 - 64. Generally only the carbonates of the Group I...Ch. 15 - 65. Many metal ions are precipitated from solution...Ch. 15 - 66. Calcium oxalate, CaCO4, is very insoluble in...Ch. 15 - 67. When aqueous solutions of lead(II) ion are...Ch. 15 - 68. Aluminum ion may be precipitated from aqueous...Ch. 15 - 69. What volume of 0.502 M NaOH solution would be...Ch. 15 - 70. What volume of a 0.500 M NaOH solution would...Ch. 15 - 71. A sample of sodium hydrogen carbonate solid...Ch. 15 - 72. The total acidity in water samples can be...Ch. 15 - Prob. 73QAPCh. 15 - Prob. 74QAPCh. 15 - Prob. 75QAPCh. 15 - Prob. 76QAPCh. 15 - 77. Explain why the equivalent weight of H2SO4 is...Ch. 15 - Prob. 78QAPCh. 15 - Prob. 79QAPCh. 15 - Prob. 80QAPCh. 15 - Prob. 81QAPCh. 15 - Prob. 82QAPCh. 15 - Prob. 83QAPCh. 15 - Prob. 84QAPCh. 15 - 85. How many milliliters of 0.50 N NaOH are...Ch. 15 - 86. What volume of 0.104 N H2SO4is required to...Ch. 15 - 87. What volume of 0.151 N NaOH is required to...Ch. 15 - Prob. 88QAPCh. 15 - 89. A mixture is prepared by mixing 50.0 g of...Ch. 15 - Prob. 90APCh. 15 - 91. Suppose 50.0 mL of 0.250 M CoCl2 solution is...Ch. 15 - Prob. 92APCh. 15 - 93. Calculate the mass of AgCl formed, and the...Ch. 15 - 94. Baking soda (sodium hydrogen carbonate....Ch. 15 - 95. Many metal ions form insoluble sulfide...Ch. 15 - Prob. 96APCh. 15 - Prob. 97APCh. 15 - Prob. 98APCh. 15 - Prob. 99APCh. 15 - Prob. 100APCh. 15 - Prob. 101APCh. 15 - You mix 225.0 mL of a 2.5 M HCl solution with...Ch. 15 - A solution is 0.1% by mass calcium chloride....Ch. 15 - Prob. 104APCh. 15 - Prob. 105APCh. 15 - A certain grade of steel is made by dissolving 5.0...Ch. 15 - Prob. 107APCh. 15 - Prob. 108APCh. 15 - Prob. 109APCh. 15 - Prob. 110APCh. 15 - How many moles of each ion are present in 11.7 mL...Ch. 15 - Prob. 112APCh. 15 - Prob. 113APCh. 15 - Prob. 114APCh. 15 - Concentrated hydrochloric acid is made by pumping...Ch. 15 - A large beaker contains 1.50 L of a 2.00 M...Ch. 15 - Prob. 117APCh. 15 - Prob. 118APCh. 15 - If 10. g of AgNO3 is available, what volume of...Ch. 15 - Prob. 120APCh. 15 - Calcium carbonate, CaCO3, can be obtained in a...Ch. 15 - Prob. 122APCh. 15 - How many milliliters of 18.0 M H2SO4 are required...Ch. 15 - Prob. 124APCh. 15 - When 10. L of water is added to 3.0 L of 6.0 M...Ch. 15 - You pour 150.0 mL of a 0.250 M lead(ll) nitrate...Ch. 15 - How many grams of Ba (NO3)2are required to...Ch. 15 - Prob. 128APCh. 15 - What volume of 0.250 M HCI is required to...Ch. 15 - Prob. 130APCh. 15 - Prob. 131APCh. 15 - Prob. 132APCh. 15 - How many milliliters of 0.105 M NaOH are required...Ch. 15 - Prob. 134APCh. 15 - Prob. 135APCh. 15 - Prob. 136APCh. 15 - Prob. 137CPCh. 15 - A solution is prepared by dissolving 0.6706 g of...Ch. 15 - What volume of 0.100 M NaOH is required to...Ch. 15 - Prob. 140CPCh. 15 - A 450.O-mL sample of a 0.257 M solution of silver...Ch. 15 - A 50.00-mL sample of aqueous Ca(OH)2 requires...Ch. 15 - When organic compounds containing sulfur are...Ch. 15 - Prob. 1CRCh. 15 - Prob. 2CRCh. 15 - Prob. 3CRCh. 15 - Prob. 4CRCh. 15 - Prob. 5CRCh. 15 - Prob. 6CRCh. 15 - Prob. 7CRCh. 15 - Prob. 8CRCh. 15 - Prob. 9CRCh. 15 - Prob. 10CRCh. 15 - Prob. 11CRCh. 15 - Without consulting your textbook, list and explain...Ch. 15 - What does “STP’ stand for? What conditions...Ch. 15 - Prob. 14CRCh. 15 - Prob. 15CRCh. 15 - Define the normal boiling point of water. Why does...Ch. 15 - Are changes in state physical or chemical changes?...Ch. 15 - Prob. 18CRCh. 15 - Prob. 19CRCh. 15 - Prob. 20CRCh. 15 - Define a crystalline solid. Describe in detail...Ch. 15 - Define the bonding that exists in metals and how...Ch. 15 - Prob. 23CRCh. 15 - Define a saturated solution. Does saturated mean...Ch. 15 - Prob. 25CRCh. 15 - When a solution is diluted by adding additional...Ch. 15 - Prob. 27CRCh. 15 - Prob. 28CRCh. 15 - Prob. 29CRCh. 15 - Prob. 30CRCh. 15 - Prob. 31CRCh. 15 - When calcium carbonate is heated strongly, it...Ch. 15 - If an electric current is passed through molten...Ch. 15 - Prob. 34CRCh. 15 - Prob. 35CRCh. 15 - Prob. 36CRCh. 15 - Prob. 37CRCh. 15 - Prob. 38CR
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