(a) Interpretation: Whether the statement “water can be made to boil at 15 °C ” is true or false is to be stated. Concept introduction: The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

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Answer 1

Question

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

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Answer 3

Question

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

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Answer 4

Question

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

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Answer 5

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Answer 6

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Answer 7

Chapter 15, Problem 15.6TC

Interpretation Introduction

(a)

Interpretation:

Whether the statement “water can be made to boil at 15°C” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the statement “bubbles can form any place in a boiling liquid” is true or false is to be stated.

Concept introduction:

The boiling point is defined as a temperature at which the conversion of a liquid into a vapor state takes place. At this temperature, the liquid’s vapor pressure becomes equal to the external pressure surrounding the liquid. The boiling point of a molecule depends upon the interactions that result from permanent or induced dipoles.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 15 - Prob. 1E Ch. 15 - Prob. 2E Ch. 15 - Prob. 3E Ch. 15 - Prob. 4E Ch. 15 - Prob. 5E Ch. 15 - Prob. 6E Ch. 15 - Prob. 7E Ch. 15 - Prob. 8E Ch. 15 - Prob. 9E Ch. 15 - Prob. 10E

Solution Summary: The author explains that the boiling point of a liquid is dependent on the atmospheric pressure and vapor pressure of the liquid.

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