Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 15, Problem 15.66P
(a)
Interpretation Introduction
Interpretation:
The alcohol whose oxidation product will be 2-methylpropanal has to be drawn.
Concept Introduction:
Oxidation:
When a carbon atom in the reactant forms more bonds to the oxygen or less bonds to hydrogen, it is said to be oxidation.
On oxidation, alcohol group is converted to carbonyl group (
(b)
Interpretation Introduction
Interpretation:
The alcohol whose oxidation product will be 2-pentanone has to be drawn.
Concept Introduction:
Oxidation:
When a carbon atom in the reactant forms more bonds to the oxygen or less bonds to hydrogen, it is said to be oxidation.
On oxidation, alcohol group is converted to carbonyl group (aldehyde or ketone) and on further oxidation, it is converted to carboxylic acid group. In mild oxidation, only one conversion occurs and primary alcohol converts to aldehyde and secondary alcohol converts to ketone.
(c)
Interpretation Introduction
Interpretation:
The alcohol whose oxidation product will be 3-methylbutanoic acid has to be drawn.
Concept Introduction:
Oxidation:
When a carbon atom in the reactant forms more bonds to the oxygen or less bonds to hydrogen, it is said to be oxidation.
On oxidation, alcohol group is converted to carbonyl group (aldehyde or ketone) and on further oxidation, it is converted to carboxylic acid group. In mild oxidation, only one conversion occurs and primary alcohol converts to aldehyde and secondary alcohol converts to ketone.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 15 Solutions
Chemistry: The Molecular Nature of Matter and Change
Ch. 15.2 - Prob. 15.1AFPCh. 15.2 - Prob. 15.1BPCh. 15.2 - Prob. 15.2APCh. 15.2 - Prob. 15.2BPCh. 15.2 - How many peaks appear in the NMR spectrum of each...Ch. 15.2 - Prob. B15.2PCh. 15.2 - Prob. B15.3PCh. 15.3 - Prob. 15.3AFPCh. 15.3 - Prob. 15.3BFPCh. 15.4 - Prob. 15.4AFP
Ch. 15.4 - Prob. 15.4BFPCh. 15.4 - Prob. 15.5AFPCh. 15.4 - Prob. 15.5BFPCh. 15.4 - Prob. 15.6AFPCh. 15.4 - Prob. 15.6BFPCh. 15.4 - Prob. 15.7AFPCh. 15.4 - Prob. 15.7BFPCh. 15.6 - Prob. 15.4PCh. 15.6 - Prob. 15.5PCh. 15 - Prob. 15.1PCh. 15 - Prob. 15.2PCh. 15 - Prob. 15.3PCh. 15 - Silicon lies just below carbon in Group 4A(14) and...Ch. 15 - What is the range of oxidation states for carbon?...Ch. 15 - Prob. 15.6PCh. 15 - Prob. 15.7PCh. 15 - Define each type of isomer: (a) constitutional;...Ch. 15 - Prob. 15.9PCh. 15 - Prob. 15.10PCh. 15 - Prob. 15.11PCh. 15 - How does an aromatic hydrocarbon differ from a...Ch. 15 - Prob. 15.13PCh. 15 - Prob. 15.14PCh. 15 - Prob. 15.15PCh. 15 - Prob. 15.16PCh. 15 - Prob. 15.17PCh. 15 - Prob. 15.18PCh. 15 - Prob. 15.19PCh. 15 - Prob. 15.20PCh. 15 - Prob. 15.21PCh. 15 - Prob. 15.22PCh. 15 - Prob. 15.23PCh. 15 - Prob. 15.24PCh. 15 - Draw structures from the following names, and...Ch. 15 - Prob. 15.26PCh. 15 - Prob. 15.27PCh. 15 - Prob. 15.28PCh. 15 - Prob. 15.29PCh. 15 - Prob. 15.30PCh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Prob. 15.34PCh. 15 - Prob. 15.35PCh. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - Determine the type of each of the following...Ch. 15 - Prob. 15.42PCh. 15 - Prob. 15.43PCh. 15 - Prob. 15.44PCh. 15 - Prob. 15.45PCh. 15 - Prob. 15.46PCh. 15 - Prob. 15.47PCh. 15 - Prob. 15.48PCh. 15 - Prob. 15.49PCh. 15 - Prob. 15.50PCh. 15 - Prob. 15.51PCh. 15 - Prob. 15.52PCh. 15 - Prob. 15.53PCh. 15 - Prob. 15.54PCh. 15 - Prob. 15.55PCh. 15 - Prob. 15.56PCh. 15 - Prob. 15.57PCh. 15 - Prob. 15.58PCh. 15 - Prob. 15.59PCh. 15 - Prob. 15.60PCh. 15 - Prob. 15.61PCh. 15 - Prob. 15.62PCh. 15 - Prob. 15.63PCh. 15 - Prob. 15.64PCh. 15 - Prob. 15.65PCh. 15 - Prob. 15.66PCh. 15 - Prob. 15.67PCh. 15 - Prob. 15.68PCh. 15 - Prob. 15.69PCh. 15 - Prob. 15.70PCh. 15 - Prob. 15.71PCh. 15 - Prob. 15.72PCh. 15 - Prob. 15.73PCh. 15 - Prob. 15.74PCh. 15 - Prob. 15.75PCh. 15 - Prob. 15.76PCh. 15 - Prob. 15.77PCh. 15 - Prob. 15.78PCh. 15 - Prob. 15.79PCh. 15 - Prob. 15.80PCh. 15 - Prob. 15.81PCh. 15 - Prob. 15.82PCh. 15 - Prob. 15.83PCh. 15 - Prob. 15.84PCh. 15 - Prob. 15.85PCh. 15 - Prob. 15.86PCh. 15 - Prob. 15.87PCh. 15 - What is the key structural difference between...Ch. 15 - Protein shape, function, and amino acid sequence...Ch. 15 - What linkage joins the monomers in each strand of...Ch. 15 - What is base pairing? How does it pertain to DNA...Ch. 15 - RNA base sequence, protein amino acid sequence,...Ch. 15 - Prob. 15.93PCh. 15 - Prob. 15.94PCh. 15 - Draw the structure of each of the following...Ch. 15 - Prob. 15.96PCh. 15 - Write the sequence of the complementary DNA strand...Ch. 15 - Prob. 15.98PCh. 15 - Prob. 15.99PCh. 15 - Prob. 15.100PCh. 15 - Prob. 15.101PCh. 15 - Amino acids have an average molar mass of 100...Ch. 15 - Prob. 15.103PCh. 15 - Prob. 15.104PCh. 15 - Some of the most useful compounds for organic...Ch. 15 - Prob. 15.106PCh. 15 - Prob. 15.107PCh. 15 - Prob. 15.108PCh. 15 - Prob. 15.109PCh. 15 - Prob. 15.110PCh. 15 - Prob. 15.111PCh. 15 - Prob. 15.112PCh. 15 - The polypeptide chain in proteins does not exhibit...Ch. 15 - Prob. 15.114PCh. 15 - Prob. 15.115PCh. 15 - Prob. 15.116PCh. 15 - Prob. 15.117PCh. 15 - Wastewater from a cheese factory has the following...Ch. 15 - Prob. 15.119P
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