ALEKS 360 ACCESS CARD F/GEN. ORG.CHEM
3rd Edition
ISBN: 9781264452545
Author: SMITH
Publisher: MCG
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Chapter 15, Problem 15.65P
Interpretation Introduction
Interpretation:
Whether the cis-2-butene and trans-2-butene are enantiomers or diastereomers should be determined.
Concept Introduction:
Stereoisomers are isomers which are having same molecular formula, same bonding arrangement but different arrangement of atoms in space.
Pair of molecules (optical isomers) that are mirror images of each other are said to be enantiomers whereas pairs that are not mirror images of each other are said to be diastereomers.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 15 Solutions
ALEKS 360 ACCESS CARD F/GEN. ORG.CHEM
Ch. 15.1 - Prob. 15.1PCh. 15.1 - For trans-2-hexene: (a) draw a stereoisomer; (b)...Ch. 15.2 - Prob. 15.3PCh. 15.2 - Prob. 15.4PCh. 15.3 - Prob. 15.5PCh. 15.3 - Prob. 15.6PCh. 15.3 - Prob. 15.7PCh. 15.3 - Prob. 15.8PCh. 15.3 - Prob. 15.9PCh. 15.3 - Prob. 15.10P
Ch. 15.3 - Prob. 15.11PCh. 15.4 - Prob. 15.12PCh. 15.4 - Prob. 15.13PCh. 15.5 - Prob. 15.14PCh. 15.6 - Prob. 15.15PCh. 15.6 - Prob. 15.16PCh. 15.6 - Prob. 15.17PCh. 15.7 - Prob. 15.18PCh. 15.7 - Prob. 15.19PCh. 15.7 - Prob. 15.20PCh. 15.7 - Prob. 15.21PCh. 15.8 - Prob. 15.22PCh. 15.8 - Prob. 15.23PCh. 15.9 - Prob. 15.24PCh. 15 - Prob. 15.25PCh. 15 - Prob. 15.26PCh. 15 - Prob. 15.27PCh. 15 - Prob. 15.28PCh. 15 - Prob. 15.29PCh. 15 - Prob. 15.30PCh. 15 - Prob. 15.31PCh. 15 - Prob. 15.32PCh. 15 - Prob. 15.33PCh. 15 - Prob. 15.34PCh. 15 - Prob. 15.35PCh. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - How are the compounds in each pair related? Are...Ch. 15 - Prob. 15.42PCh. 15 - Prob. 15.43PCh. 15 - Prob. 15.44PCh. 15 - Answer each question with a compound of molecular...Ch. 15 - Prob. 15.46PCh. 15 - Prob. 15.47PCh. 15 - Prob. 15.48PCh. 15 - Prob. 15.49PCh. 15 - Prob. 15.50PCh. 15 - Prob. 15.51PCh. 15 - Prob. 15.52PCh. 15 - Prob. 15.53PCh. 15 - Prob. 15.54PCh. 15 - Prob. 15.55PCh. 15 - Prob. 15.56PCh. 15 - (a) Define the terms “optically active” and...Ch. 15 - Prob. 15.58PCh. 15 - Prob. 15.59PCh. 15 - Prob. 15.60PCh. 15 - Prob. 15.61PCh. 15 - Prob. 15.62PCh. 15 - Prob. 15.63PCh. 15 - Prob. 15.64PCh. 15 - Prob. 15.65PCh. 15 - Prob. 15.66PCh. 15 - Prob. 15.67PCh. 15 - Prob. 15.68PCh. 15 - Prob. 15.69PCh. 15 - Prob. 15.70PCh. 15 - Prob. 15.71PCh. 15 - Prob. 15.72PCh. 15 - Prob. 15.73CPCh. 15 - Prob. 15.74CP
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