The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated. Concept introduction: The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Question

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Answer 1

Question

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

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Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate

Using the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI A

Answer 2

Question

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

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Answer 3

Question

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

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Answer 4

Question

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

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Answer 5

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 6

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 7

Chapter 15, Problem 15.37SP

(a)

Interpretation Introduction

Interpretation:

The resonance forms of pentadienyl radical to show the three carbon atoms that bear unpaired electron are to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of molecular orbitals in the molecular orbital picture of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of nodes presents in lower-energy molecular orbital and highest-energy molecular orbital of pentadienyl radical is to be predicted.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The molecular orbitals of pentadienyl system in order of increasing energy are to be drawn.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The number of electrons present in each molecular orbital of pentadienyl radical is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 16

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 17

(f)

Interpretation Introduction

Interpretation:

An explanation to show that molecular orbital picture agrees with the resonance picture that shows the delocalization of unpaired electron on the three carbon atoms is to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The carbon atoms that share the positive charge and the picture agree with the resonance structure or not are to be stated.

Concept introduction:

Molecular orbital diagrams are used for determining the bonding in molecules using linear combination of atomic orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals that combine with each other.

Answer 22

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Answer 23

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Answer 24

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Answer 25

Ch. 15.2 - Prob. 15.1P Ch. 15.2 - Prob. 15.2P Ch. 15.2 - Prob. 15.3P Ch. 15.4 - Prob. 15.4P Ch. 15.4 - Prob. 15.5P Ch. 15.5 - Treatment of an alkyl halide with AgNO3 in alcohol...Ch. 15.5 - Propose a mechanism for each reaction, showing...Ch. 15.6 - When Br2 is added to buta-1,3-diene at 15 C, the...Ch. 15.7 - Prob. 15.9P Ch. 15.7 - When N-bromosuccinimide is added to hex-1-ene in...

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Chapter 15 Solutions