The product of light-initiated reaction of cyclopentene with NBS in CCl 4 is to be predicted. Concept introduction: NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

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Answer 1

Question

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

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Answer 2

Question

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Expert Solution & Answer

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Answer 3

Question

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Expert Solution & Answer

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Answer 4

Question

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Expert Solution & Answer

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Answer 5

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 6

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 7

Chapter 15.7, Problem 15.11P

(a)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of cyclopentene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of 2,3-dimethylbut-2-ene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The product of light-initiated reaction of toluene with NBS in CCl4 is to be predicted.

Concept introduction:

NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and occupy that position when it is exposed to light. The mechanism of the reaction involves the formation of allylic radical which shows resonating structures due to presence of adjacent double bond.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 15.2 - Prob. 15.1P Ch. 15.2 - Prob. 15.2P Ch. 15.2 - Prob. 15.3P Ch. 15.4 - Prob. 15.4P Ch. 15.4 - Prob. 15.5P Ch. 15.5 - Treatment of an alkyl halide with AgNO3 in alcohol...Ch. 15.5 - Propose a mechanism for each reaction, showing...Ch. 15.6 - When Br2 is added to buta-1,3-diene at 15 C, the...Ch. 15.7 - Prob. 15.9P Ch. 15.7 - When N-bromosuccinimide is added to hex-1-ene in...

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