Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 15, Problem 15.27SP

(a)

Interpretation Introduction

Interpretation:

The resonance contributor for the given cation is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

An electron deficient carbon atom that can accept the incoming nucleophile is known as carbocation. Carbocation shows resonance structures when double bond is present in conjugation with it.

(b)

Interpretation Introduction

Interpretation:

The resonance contributor for the given free radical is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

(c)

Interpretation Introduction

Interpretation:

The resonance contributor for the given anion is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron rich carbon atom that can accept the incoming electrophile is known as carbanion. Carbanion shows resonance structures, when double bond is present in conjugation with it.

(d)

Interpretation Introduction

Interpretation:

The resonance contributor for the given cation is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron deficient carbon atom that can accept the incoming nucleophile is known as carbocation. Carbocation shows resonance structures when double bond is present in conjugation with it.

(e)

Interpretation Introduction

Interpretation:

The resonance contributor for the given anion is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron rich carbon atom that can accept the incoming electrophile is known as carbanion. Carbanion shows resonance structures, when double bond is present in conjugation with it.

(f)

Interpretation Introduction

Interpretation:

The resonance contributor for the given anion is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron rich carbon atom that can accept the incoming electrophile is known as carbanion. Carbanion shows resonance structures, when double bond is present in conjugation with it.

(g)

Interpretation Introduction

Interpretation:

The resonance contributor for the given cation is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron deficient carbon atom that can accept the incoming nucleophile is known as carbocation. Carbocation shows resonance structures when double bond is present in conjugation with it.

(h)

Interpretation Introduction

Interpretation:

The resonance contributor for the given cation is to be stated.

Concept introduction:

The delocalization of lone pair or free electrons from one place to another is known as resonance. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

An electron deficient carbon atom that can accept the incoming nucleophile is known as carbocation. Carbocation shows resonance structures when double bond is present in conjugation with it.

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3. Draw all resonance structures for the following radicals.
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Curved arrows are used to illustrate the flow of electrons. Using the provided resonance structures, draw the curved electron- pushing arrows to show the interconversion between resonance hybrid contributors. Be sure to account for all bond- breaking and bond-making steps. I I I I :O: f

Chapter 15 Solutions

Organic Chemistry (9th Edition)

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