Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 15, Problem 15.33P
Interpretation Introduction

Interpretation:

The description of liquid-based ion-selective electrode specific for one analyte has to be explained.

Concept introduction:

Liquid based ion-selective electrode:

A class of ion-selective electrodes utilizes a hydrophobic membrane consist of a liquid organic complexing agent which reacts selectively with the analyte.

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.
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