
Interpretation:
The cell voltage at each volume of
Concept Introduction:-
Cell Voltage:
Cell voltage is the difference between cathode potential and anode potential.
The unreacted concentration in the solution is determined by
Ion-selective electrode:
An ion-selective electrode (ISE) best known as a specific ion electrode (SIE), is a sensor (or transducer) that transforms the activity of a specific ion dissolved in a solution into an electrical potential.
Ion-selective electrode obeys following equation.

Explanation of Solution
Given:
The titration reaction is a reduction reaction.
The cell voltage of the reaction is written as
Cell Voltage:
Cell voltage is the difference between cathode potential and anode potential.
Where,
Another titration reaction is
The solubility constant for
The given equivalence point is
The unreacted
At
At
At
At
After
At
At
At
All the obtained potential are plotted as,
Figure 1
The cell voltage at each volume of
Want to see more full solutions like this?
Chapter 15 Solutions
Quantitative Chemical Analysis
- Calculate the pH and the pOH of each of the following solutions at 25 °C for which the substances ionize completely: (a) 0.000259 M HClO4arrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardDetermine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃arrow_forward
- A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol b. 3,4-Dimethyl-1-pentanol c. 4-Ethyl-2-heptanol d. 5,7-Dichloro-3-heptanolarrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardCan I please get help with this.arrow_forward
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. N₂H₅ClO₄arrow_forwardPlease help me with identifying these.arrow_forwardCan I please get help with this?arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





