
Concept explainers
(a)
Interpretation:
The target molecule transformation should be draw and identified given the starting molecule of
Concept Introduction:
Oxidation Reaction: Generally alcohol can be oxidizing to aldehyde or
Reduction Reaction: This process in which any substance atoms, ion or molecule gains one or more electrons it is called reduction.
(a)

Answer to Problem 15.20UKC
The hydride added to the carbonyl carbon, the polar (C=O) carbon has a partial positive charge, then the reduction process has
Explanation of Solution
Reduction reaction: The given carbonyl molecule is converted into alcohol (b) in this undergoes for reduction process was occurred. The hydride ion added to the carbonyl carbon, because carbonyl carbon is polar it as partial positive charges in carbon atom.
(b)
To determine give the reactions indicate which direction represents reduction and which represents oxidation.
Concept Introduction:
Carbonyl group: This group presence of a
Oxidation Reaction: Generally alcohol can be oxidizing to aldehyde or ketone and aldehyde can be further oxidized to carboxylic acids.
Reduction Reaction: This process in which any substance atoms, ion or molecule gains one or more electrons it is called reduction.
(b)

Answer to Problem 15.20UKC
Given the arrow to the right represents reduction and the arrow to the left represents oxidation.
Explanation of Solution
Let us consider given reaction,
Given the arrow to the right represents reduction and the arrow to the left represents oxidation.
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Chapter 15 Solutions
Fundamentals of General, Organic, and Biological Chemistry, Books a la Carte Edition; Modified Mastering Chemistry with Pearson eText -- ValuePack ... and Biological Chemistry (4th Edition)
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- Sodium fluoroacetate (FCH 2CO2Na) is a very toxic molecule that is used as rodentpoison. It is converted enzymatically to fluoroacetyl-CoA and is utilized by citratesynthase to generate (2R,3S)-fluorocitrate. The release of this product is a potentinhibitor of the next enzyme in the TCA cycle. Show the mechanism for theproduction of fluorocitrate and explain how this molecule acts as a competitiveinhibitor. Predict the effect on the concentrations of TCA intermediates.arrow_forwardIndicate for the reactions below which type of enzyme and cofactor(s) (if any) wouldbe required to catalyze each reaction shown. 1) Fru-6-P + Ery-4-P <--> GAP + Sed-7-P2) Fru-6-P + Pi <--> Fru-1,6-BP + H2O3) GTP + ADP <--> GDP + ATP4) Sed-7-P + GAP <--> Rib-5-P + Xyl-5-P5) Oxaloacetate + GTP ---> PEP + GDP + CO 26) DHAP + Ery-4-P <--> Sed-1,7-BP + H 2O7) Pyruvate + ATP + HCO3- ---> Oxaloacetate + ADP + Piarrow_forwardTPP is also utilized in transketolase reactions in the PPP. Give a mechanism for theTPP-dependent reaction between Xylulose-5-phosphate and Ribose-5-Phosphate toyield Glyceraldehyde-3-phosphate and Sedoheptulose-7-Phosphate.arrow_forward
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