The reagents are to be identified for Synthesis of Racemic mixture of Epoxides . Concept Introduction: Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins Epoxides from Peroxy acids: The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific. Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide. Epoxides from Halohydrins: Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

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Answer 1

Question

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

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Answer 2

Question

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

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Answer 3

Question

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

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Answer 4

Question

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

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Answer 5

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 6

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 7

Chapter 14.8, Problem 14PTS

(a)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 8

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 9

(b)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 10

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 11

(c)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 12

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 13

(d)

Interpretation Introduction

Interpretation: The reagents are to be identified for Synthesis of Racemic mixture of Epoxides.

Concept Introduction:

Epoxides are obtained by the conversion of Alkene using Peroxy acids and Halohydrins

Epoxides from Peroxy acids:

The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.

Specifically, the substituent are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituent’s are trans to each other in starting Alkene remains trans to each other in Epoxide.

Epoxides from Halohydrins:

Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 14.2 - Prob. 1LTS Ch. 14.2 - Prob. 1PTS Ch. 14.2 - Prob. 2ATS Ch. 14.2 - Prob. 3ATS Ch. 14.4 - Prob. 4CC Ch. 14.5 - Prob. 2LTS Ch. 14.5 - Prob. 5PTS Ch. 14.5 - Prob. 6ATS Ch. 14.5 - Prob. 7ATS Ch. 14.5 - Prob. 8CC

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Chapter 14 Solutions