Student Study Guide and Solutions Manual T/A Organic Chemistry
Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 14.9, Problem 16CC

a)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  1

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  2       Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  3

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  4

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  5

To predict the product of reaction

b)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  6

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  7       Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  8

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  9

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  10

To predict the product of reaction

c)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  11

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  12       Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  13

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  14

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  15

To predict the product of reaction

d)

Interpretation Introduction

Interpretation: The products for the following reactions are to be predicted.

Concept Introduction:

Sharpless epoxidation: An Alkene containing a Hydroxyl group in the allylic position is called as Allylic alcohols. Allylic position is the position next to C=C bond.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  16

Sharpless catalyst consists of Titanium tetraiospropoxide and one enantiomer of Diethyl tartrate ( DET )

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  17       Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  18

A chiral complex is formed with Titanium tetraisopropoxide and with either +DET or -DET , and this complex serves as the chiral catalyst.

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  19

Student Study Guide and Solutions Manual T/A Organic Chemistry, Chapter 14.9, Problem 16CC , additional homework tip  20

To predict the product of reaction

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Student Study Guide and Solutions Manual T/A Organic Chemistry

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