(a)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from
Useful reagents:
- 1.
(b)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(c)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(d)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(e)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(f)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(g)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
(h)
Interpretation: The products for the given reactions to be identified.
Concept Introduction:
Ring-opening of epoxide: The epoxide ring is highly strain and readily undergoes reaction with strong nucleophile result in the ring-opening reaction.
Regiochemistry: when the epoxide is unsymmetrical, the nucleophile attack at the less substituted position.
Stereochemistry: when the nucleophile attack takes place at chiral center, an inversion of configuration is obtained.
Alkoxymercuration-demercuration: the process where alcohols can be prepared from alkene, results in the markovnikov’s addition of
Useful reagents:
- 1.
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Chapter 14 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
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