Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Chapter 14.8, Problem 3LTS
Interpretation Introduction
Interpretation: Synthesis of
Concept Introduction:
Epoxides are obtained by the conversion of
Epoxides from Peroxy acids:
The commonly used Peroxy acids are meta-Chloroperoxybenzoic acid (MCPBA) and Peroxyacetic acid. This process is stereospecific.
Specifically, the substituents are cis to each other in starting Alkene remains cis to each other in Epoxide, and the substituents are trans to each other in starting Alkene remains trans to each other in Epoxide.
Epoxides from Halohydrins:
Epoxides can be obtained by the conversion of Alkene to Halohydrins. Halohydrins are formed when an Alkene is treated with halogen in presence of Water. Halohydrins formed are later treated with strong base to from Epoxides.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
Submit
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 14 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
Ch. 14.2 - Prob. 1LTSCh. 14.2 - Prob. 1PTSCh. 14.2 - Prob. 2ATSCh. 14.2 - Prob. 3ATSCh. 14.4 - Prob. 4CCCh. 14.5 - Prob. 2LTSCh. 14.5 - Prob. 5PTSCh. 14.5 - Prob. 6ATSCh. 14.5 - Prob. 7ATSCh. 14.5 - Prob. 8CC
Ch. 14.5 - Prob. 9CCCh. 14.5 - Prob. 10CCCh. 14.6 - Prob. 11CCCh. 14.7 - Prob. 12CCCh. 14.7 - Prob. 13CCCh. 14.8 - Prob. 3LTSCh. 14.8 - Prob. 14PTSCh. 14.8 - Prob. 15ATSCh. 14.9 - Prob. 16CCCh. 14.10 - Prob. 4LTSCh. 14.10 - Prob. 17PTSCh. 14.10 - Prob. 18ATSCh. 14.10 - Prob. 19ATSCh. 14.10 - Prob. 5LTSCh. 14.10 - Prob. 20PTSCh. 14.10 - Prob. 21ATSCh. 14.11 - Prob. 22CCCh. 14.11 - Prob. 23CCCh. 14.12 - Prob. 6LTSCh. 14.12 - Prob. 24PTSCh. 14.12 - Prob. 25ATSCh. 14.12 - Prob. 7LTSCh. 14.12 - Prob. 26PTSCh. 14.12 - Prob. 27ATSCh. 14.12 - Prob. 28ATSCh. 14.12 - Prob. 29ATSCh. 14 - Prob. 30PPCh. 14 - Prob. 31PPCh. 14 - Prob. 32PPCh. 14 - Prob. 33PPCh. 14 - Prob. 34PPCh. 14 - Prob. 35PPCh. 14 - Prob. 36PPCh. 14 - Prob. 37PPCh. 14 - Prob. 38PPCh. 14 - Prob. 39PPCh. 14 - Prob. 40PPCh. 14 - Prob. 41PPCh. 14 - Prob. 42PPCh. 14 - Prob. 43PPCh. 14 - Prob. 44PPCh. 14 - Prob. 45PPCh. 14 - Prob. 46PPCh. 14 - Prob. 47PPCh. 14 - Prob. 48PPCh. 14 - Prob. 49PPCh. 14 - Prob. 50PPCh. 14 - Prob. 51IPCh. 14 - Prob. 52IPCh. 14 - Prob. 53IPCh. 14 - Prob. 54IPCh. 14 - Prob. 55IPCh. 14 - Prob. 56IPCh. 14 - Prob. 57IPCh. 14 - Prob. 58IPCh. 14 - Prob. 59IPCh. 14 - Prob. 60IPCh. 14 - Prob. 61IPCh. 14 - Prob. 62IPCh. 14 - Prob. 63IP
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