Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
3rd Edition
ISBN: 9780137533268
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 14.2, Problem 2P
Interpretation Introduction
Interpretation:
Initiation, propagation and termination steps for the monochlorination of cydohexane should be written.
Concept introduction:
Radical or free radical:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
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Provide reactions showing the following conversions: * see image
. Draw structures corresponding to each of the following names or Provide IUPAC names for each of the
ollowing structures [for 4 ONLY].
A. 2-propylpentanoic acid.
B. m-chlorobenzoic acid.
D.
C.
O
O
HOC(CH2)3COH glutaricadd
OH
OH
H3C
CH3
C=C
H
COOH
salicylicadd
tiglicadd
CH₂C=N
Joe M
. Provide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the
ollowing reactions or sequences of reactions. Show all relevant stereochemistry [five only]
A.
O
B.
OET
CH3
1. LIAIH, ether
2 H₂O
O
(CH3)2CH-C-CI +
0
0
ether (CH3)2CH-C-O-C-CH3
CH3
C.
0
OH
HO
CH3
°
Cl
Chapter 14 Solutions
Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
Ch. 14.2 - Write the mechanism for the monobromination of...Ch. 14.2 - Prob. 2PCh. 14.4 - Prob. 3PCh. 14.4 - Which of the hydrogens in the structure in the...Ch. 14.4 - How many alkyl chlorides can be obtained from...Ch. 14.4 - Prob. 7PCh. 14.5 - Prob. 9PCh. 14.6 - a. Which ether is most apt to form a peroxide? b....Ch. 14.7 - Prob. 11PCh. 14 - Prob. 12P
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