Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+)
3rd Edition
ISBN: 9780137533268
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 14, Problem 14P

(a)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with bromine in presence of light at room temperature should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

In a halogenation reaction, one or more halogen atoms are introduced into an organic compound. Generally, these reactions are initiated in the presence of light or heat.

Bromination:

Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+), Chapter 14, Problem 14P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with bromine in presence of light at room temperature should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

In a halogenation reaction, one or more halogen atoms are introduced into an organic compound. Generally, these reactions are initiated in the presence of light or heat.

Bromination:

Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+), Chapter 14, Problem 14P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with bromine in presence of light at room temperature should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

In a halogenation reaction, one or more halogen atoms are introduced into an organic compound. Generally, these reactions are initiated in the presence of light or heat.

Bromination:

Pearson eText for Essential Organic Chemistry -- Instant Access (Pearson+), Chapter 14, Problem 14P , additional homework tip  3

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z
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