Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
12th Edition
ISBN: 9780321908445
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 14.2, Problem 14.9QAP
Identify the compound in each group that is most soluble in water. Explain.
a. propanoic acid, hexanoic acid, benzoic acid
b. pentane, 1-hexanol, propanoic acid
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 14 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
Ch. 14.1 - What carboxylic acid is responsible for the pain...Ch. 14.1 - What carboxylic acid is found in vinegar?Ch. 14.1 - Prob. 14.3QAPCh. 14.1 - Prob. 14.4QAPCh. 14.1 - Prob. 14.5QAPCh. 14.1 - Prob. 14.6QAPCh. 14.1 - Draw the condensed structural formulas for a and b...Ch. 14.1 - Draw the condensed structural formulas for a and b...Ch. 14.2 - Identify the compound in each group that is most...Ch. 14.2 - Prob. 14.10QAP
Ch. 14.2 - Prob. 14.11QAPCh. 14.2 - Prob. 14.12QAPCh. 14.2 - Prob. 14.13QAPCh. 14.2 - Prob. 14.14QAPCh. 14.3 - Prob. 14.15QAPCh. 14.3 - Prob. 14.16QAPCh. 14.3 - Prob. 14.17QAPCh. 14.3 - Prob. 14.18QAPCh. 14.3 - Prob. 14.19QAPCh. 14.3 - Prob. 14.20QAPCh. 14.3 - Prob. 14.21QAPCh. 14.3 - Prob. 14.22QAPCh. 14.3 - Prob. 14.23QAPCh. 14.3 - Prob. 14.24QAPCh. 14.4 - What are the products of the acid hydrolysis of an...Ch. 14.4 - Prob. 14.26QAPCh. 14.4 - Prob. 14.27QAPCh. 14.4 - Prob. 14.28QAPCh. 14.5 - Prob. 14.29QAPCh. 14.5 - Prob. 14.30QAPCh. 14.5 - Prob. 14.31QAPCh. 14.5 - Prob. 14.32QAPCh. 14.5 - Prob. 14.33QAPCh. 14.5 - Prob. 14.34QAPCh. 14.5 - Prob. 14.35QAPCh. 14.5 - Prob. 14.36QAPCh. 14.5 - Prob. 14.37QAPCh. 14.5 - Prob. 14.38QAPCh. 14.6 - Prob. 14.39QAPCh. 14.6 - Prob. 14.40QAPCh. 14.6 - Prob. 14.41QAPCh. 14.6 - Prob. 14.42QAPCh. 14.6 - Prob. 14.43QAPCh. 14.6 - Prob. 14.44QAPCh. 14.6 - Prob. 14.45QAPCh. 14.6 - Prob. 14.46QAPCh. 14 - Prob. 14.47UTCCh. 14 - Prob. 14.48UTCCh. 14 - The ester methyl butanoate has the odor and flavor...Ch. 14 - Prob. 14.50UTCCh. 14 - Prob. 14.51UTCCh. 14 - Melatonin is a naturally occurring compound in...Ch. 14 - Prob. 14.53UTCCh. 14 - Prob. 14.54UTCCh. 14 - Prob. 14.55AQAPCh. 14 - Prob. 14.56AQAPCh. 14 - Prob. 14.57AQAPCh. 14 - Prob. 14.58AQAPCh. 14 - Prob. 14.59AQAPCh. 14 - Prob. 14.60AQAPCh. 14 - Prob. 14.61AQAPCh. 14 - Prob. 14.62AQAPCh. 14 - Prob. 14.63AQAPCh. 14 - Prob. 14.64AQAPCh. 14 - Prob. 14.65AQAPCh. 14 - Prob. 14.66AQAPCh. 14 - Prob. 14.67AQAPCh. 14 - Prob. 14.68AQAPCh. 14 - Prob. 14.69AQAPCh. 14 - Prob. 14.70AQAPCh. 14 - Prob. 14.71AQAPCh. 14 - Prob. 14.72AQAPCh. 14 - Prob. 14.73AQAPCh. 14 - Prob. 14.74AQAPCh. 14 - Prob. 14.75CQCh. 14 - Prob. 14.76CQCh. 14 - Prob. 14.77CQCh. 14 - Prob. 14.78CQ
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