Problem 1E: Which of the following do you expect to be most water soluble, and why?... Problem 2E: Which of the following is moderately soluble both in water and in benzene, C8H8(l) and why? (a) CH2(... Problem 3E: Substances that dissolve in water generally do not dissolve in benzene. Some substances are... Problem 4E Problem 5E: Two of the substances listed here highly soluble in water, two are only slightly soluble in water,... Problem 6E: Benzoic acid, C8H8COOH, is much more soluble in NaOH(aq) than it is in pure water. Can you suggest... Problem 7E Problem 8E: Explain the observation that all metal nitrates are water soluble but many metal sulfides are not.... Problem 9E: A saturated aqueous solution of NaBr at 20C contains 116 g NaBr/100 g H2O . Express this composition... Problem 10E Problem 11E Problem 12E: You are asked to prepare 125.0 mL of 0.0321 M AgNO2 . How many grams would you need of a sample... Problem 13E Problem 14E Problem 15E Problem 16E Problem 17E: The sulfate ion level in a municipal water supply is given as 461 ppm. What is [SO42-] in this... Problem 18E: A water sample is found to have 9.4 ppb of chloroform, CHCl2 . How many grams of CHCl2 would be... Problem 19E Problem 20E Problem 21E: How many milliliters at the ethanol-water solution described in Example 14.1 should be diluted with... Problem 22E Problem 23E: What is the molarity of CO2 in liter ocean water at 25C that contains approxmately 280 ppm of CO2 ?... Problem 24E Problem 25E Problem 26E Problem 27E: How many grams of iodine, l2 , must be dissolved in 725 mL of carbon disulfide, CS2(d=1.261g/mL) ,... Problem 28E: How many grams of water would you add to 1.00 kg of 1.38 mol kg-1 CH2OH (aq) to reduce the molality... Problem 29E Problem 30E: A 10.00%-by-man solution of ethanol, CH2CH2OH , in water has a density 0.9831 g/mL at 15C and 0.9804... Problem 31E Problem 32E Problem 33E Problem 34E Problem 35E: What volume of glycerol, CH2CH(OH)CH2OH(d=1.26g/mL) , must be added kilogram of water to solution... Problem 36E Problem 37E Problem 38E: The amount of CO2 in the ocean is approximately 280 ppm. What is the mole fraction of CO2 in a titer... Problem 39E Problem 40E Problem 41E Problem 42E Problem 43E: Under an O2(g) pressure of 1.00 atm, 28.31mL of O2(g) dissolves in 1.00LH2O at 25C . What will be... Problem 44E Problem 45E: Natural gas consists about 90% methane, CM. Assume that the solubility of natural gas at 20C and 1... Problem 46E: At 1.00 atm, the solubility of O2 in water is 2.18102 M at 25C . What volume of O2(g) , measured at... Problem 47E: The aqueous solubility at 20C of Ar at 1.00 atm equivalent to10337 ml. Ar(g), measured at 0C and... Problem 48E Problem 49E Problem 50E Problem 51E: What are the partial and total vapor pressures of a solution obtained by mixing 35.8g benzene, C8H8... Problem 52E Problem 53E: Calculate the vapor pressure at 25C of a solution containing 165g of the nonvolatile solute,... Problem 54E: Calculate the vapor pressure at 20C of a saturated solution of the nonvolatile solute, urea, CO(... Problem 55E: Styrene, used in the manufacture of polystyrene plastics, is made by the extraction of hydrogen... Problem 56E Problem 57E: A benzene-toluene solution with banz=0.300 has a normal boiling point of 98.6C . The vapor pressure... Problem 58E Problem 59E Problem 60E Problem 61E Problem 62E Problem 63E Problem 64E Problem 65E Problem 66E: Use the concentration of an istonic solution, 0.92% NaCl (mass/volume), to determine the osmotic... Problem 67E Problem 68E: The two solutions pictured here are separated by a semipermeable membrane that permits only the... Problem 69E: of an unknown compound reduces e freezing point of 7522g benzene from 553 to 4.92C . What is the... Problem 70E Problem 71E Problem 72E Problem 73E: A compound is 42.9% C, 2.4% H, 16.7%N, and 38.1% O, by mass. Addition of 6.45g of this compound to... Problem 74E: Nicotinamide is a water-soluble vitamin important in metabolism. A deficiency in the vitamin result... Problem 75E Problem 76E: Coniferin is glycoside (a derivative of a sugar) found in conifers, such as fir tress. When a 1.205... Problem 77E: Cooks often add some salt to water before boding Some people say the hems me cooking process by... Problem 78E: An important test for the purity of an organic compound is to measure its melting point. Usually, it... Problem 79E Problem 80E: If ocean water consisted of 3.5% salt, what would be the freezing point of an ocean? Problem 81E: Predict the approximate freezing points of 0.10m solutions of the following solutes dissolved in... Problem 82E: Calculate the van’t Hoff factors of the following weak electrolyte solutions: a. 0.050 m HCOOH,... Problem 83E: NH2(aq) conducts electric current only weakly. The same is true for acetic acid, CH2COOH . When... Problem 84E Problem 85E Problem 86E Problem 87IAE Problem 88IAE Problem 89IAE Problem 90IAE Problem 91IAE: A solid mixture consists of 85.0% KNO2 and 15.0% K2SO4 , by mass. A 60.0 g sample of this solid is... Problem 92IAE: Suppose you have available 2.50 L of a solution (d = 0.9767 g/mL) that is 138% ethanol ( CH1CH2OH ),... Problem 93IAE Problem 94IAE Problem 95IAE Problem 96IAE: Nitrobenzene, C6H2NO2 , and benzene, C6H8 , are completely miscible in each other properties of the... Problem 97IAE Problem 98IAE Problem 99IAE Problem 100IAE: Suppose that I 00mg of gold obtained in a colloidal dispersion in which the gold particles are... Problem 101IAE: At 20C , liquid benzene has a density of 0.879g/cm2 ; liquid toluene, 0.867g/cm2 . Assume ideal... Problem 102IAE: The two compounds whose structures are depicted here are isomers. When derived from petroplem, they... Problem 103IAE Problem 104IAE Problem 105IAE Problem 106IAE: We noted m Figure 14-17 that the liquid and vapor curves taken together outline a lens-shaped region... Problem 107IAE: A saturated solution prepared at 70C contains 32.0gCuSO4 per 100.0 per solution. A 335 g sample of... Problem 108IAE Problem 109IAE Problem 110IAE Problem 111IAE Problem 112IAE Problem 113FP Problem 114FP: The phase diagram shown is for mixtures of HCI and H2O at a pressure of 1 atm. The red curve... Problem 115FP: The laboratory device pictured on the following page is called a desiccators. It can be used to... Problem 116FP Problem 117SAE Problem 118SAE: Briefly describe each of the following ides or phenomena: (a) Henry’s law; (b) freezing-point... Problem 119SAE: Explain the important distinctions between each pair of terms: (a) molality and molarity (b) ideal... Problem 120SAE Problem 121SAE Problem 122SAE Problem 123SAE Problem 124SAE: An ideal liquid solution has two volatile components. In the vapor in equilibrium with the solution,... Problem 125SAE Problem 126SAE Problem 127SAE: A solution (d=1.159g/mL) is 62.0% glycerol, HOCH2CH(OH)CH2OH , and 38.0% H2O , by mass Determine (a)... Problem 128SAE Problem 129SAE Problem 130SAE Problem 131SAE Problem 132SAE Problem 133SAE Problem 134SAE: What is the mole fractions of a monvolatile solute in a hexane solution that has a vapor pressure of... Problem 135SAE: What is the osmotic pressure, in bar, of 15.2L of a 0.312M starch solution at 75C ? (a) 13721.1; (b)... Problem 136SAE: What is the weight percent of 23.4 g of CaF2 if dissolved in 10.5 mol of water? (a) 0.028; (b) 1.59;... Problem 137SAE Problem 138SAE format_list_bulleted