Determine the pOH of each solution and classify it as acidic, basic, or neutral. a. [ OH − ] = 4.5 × 10 − 2 M b. [ OH − ] = 3.1 × 10 − 12 M c. [ OH − ] = 5.4 × 10 − 5 M d. [ OH − ] = 1.2 × 10 − 2 M
Determine the pOH of each solution and classify it as acidic, basic, or neutral. a. [ OH − ] = 4.5 × 10 − 2 M b. [ OH − ] = 3.1 × 10 − 12 M c. [ OH − ] = 5.4 × 10 − 5 M d. [ OH − ] = 1.2 × 10 − 2 M
Solution Summary: The author explains that the pOH of a solution is the negative of the logarithm of hydroxide ion concentration.
bre
The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
wolsd works 2
NH2
NaNO2, HCI
(apexe) 13× (1
HNO3, H2SO4
C6H5CIN2
0°C
HOTE
CHINO₂
N
O
*O₂H (
PO
Q
Я
Scheme 5
2 bag abouoqmics to sounde odi WEIC
(i)
Draw the structure of intermediate O.
[2 marks]
to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa
(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
Spoilage
(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
[tom E
P.
vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx
(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
bus noires goiribbeolovo xnivollot adj to subora sidab
Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
vi
(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 14 Solutions
Introductory Chemistry, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (5th Edition)
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