For the given table, the missing hydrogen ion concentration [ H 3 O + ] , hydroxide ion concentration [ OH − ] , pH, pOH and nature of the solution should be determined. Concept information: The pH of a solution is expressed by the formula as follows: pH = − log [ H 3 O + ] The pH scale is used to classify the solution as follows: The solution having pH value less than 7 is acidic. The solution having pH value greater than 7 is basic. If the solution has pH equal to 7, then it is neutral. The pOH of a solution is expressed by the formula as follows: pOH = − log [ OH − ] The sum of pOH and pH of a solution is equal to 14. pOH + pH = 14.0 The ion product constant is expressed as follows: [ H 3 O + ] [ OH − ] = K w = 1.0 × 10 − 14 The solution is acidic if the concentration of hydronium ions is less than 1.0 × 10 − 7 M and vice-versa. The solution is basic if concentration of hydroxide ions is more than 1.0 × 10 7 M 1.0 × 10 − 7 M and vice-versa.
For the given table, the missing hydrogen ion concentration [ H 3 O + ] , hydroxide ion concentration [ OH − ] , pH, pOH and nature of the solution should be determined. Concept information: The pH of a solution is expressed by the formula as follows: pH = − log [ H 3 O + ] The pH scale is used to classify the solution as follows: The solution having pH value less than 7 is acidic. The solution having pH value greater than 7 is basic. If the solution has pH equal to 7, then it is neutral. The pOH of a solution is expressed by the formula as follows: pOH = − log [ OH − ] The sum of pOH and pH of a solution is equal to 14. pOH + pH = 14.0 The ion product constant is expressed as follows: [ H 3 O + ] [ OH − ] = K w = 1.0 × 10 − 14 The solution is acidic if the concentration of hydronium ions is less than 1.0 × 10 − 7 M and vice-versa. The solution is basic if concentration of hydroxide ions is more than 1.0 × 10 7 M 1.0 × 10 − 7 M and vice-versa.
Solution Summary: The author explains how the pH, pOH, and nature of the solution should be determined for the given table.
For the given table, the missing hydrogen ion concentration [H3O+], hydroxide ion concentration [OH−], pH, pOH and nature of the solution should be determined.
Concept information:
The pH of a solution is expressed by the formula as follows:
pH=−log[H3O+]
The pH scale is used to classify the solution as follows:
The solution having pH value less than 7 is acidic.
The solution having pH value greater than 7 is basic.
If the solution has pH equal to 7, then it is neutral.
The pOH of a solution is expressed by the formula as follows:
pOH=−log[OH−]
The sum of pOH and pH of a solution is equal to 14.
pOH+pH=14.0
The ion product constant is expressed as follows:
[H3O+][OH−]=Kw=1.0×10−14
The solution is acidic if the concentration of hydronium ions is less than 1.0×10−7M and vice-versa.
The solution is basic if concentration of hydroxide ions is more than 1.0×107M1.0×10−7M and vice-versa.
bre
The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
wolsd works 2
NH2
NaNO2, HCI
(apexe) 13× (1
HNO3, H2SO4
C6H5CIN2
0°C
HOTE
CHINO₂
N
O
*O₂H (
PO
Q
Я
Scheme 5
2 bag abouoqmics to sounde odi WEIC
(i)
Draw the structure of intermediate O.
[2 marks]
to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa
(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
Spoilage
(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
[tom E
P.
vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx
(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
bus noires goiribbeolovo xnivollot adj to subora sidab
Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
vi
(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 14 Solutions
Introductory Chemistry, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (5th Edition)
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