
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Question
Chapter 14, Problem 56DSP
Interpretation Introduction
Interpretation:
The correct statement is to be chosen.
Concept introduction:
The magnitude of coupling constant depends on the dihedral angle.
The coupling constant is the greatest when the dihedral angle is
The coupling constant of protons which are di equatorial is between
The coupling constant of protons which are axial/equatorial is between
The coupling constant of protons which are di axial is between
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Which of the following is the product of the reaction between acetone, CH3COCH3 and methyl amine, CH3NH2? Why is the correct answer A? Please explain what is happening. Please include a detailed explanation and a drawing of steps needed to understand the reaction or question.
What is the product of the reaction shown below? Why is the correct answer D? Please explain what is happening. Please include a detailed explanation and a drawing of steps needed to understand the reaction or question.
Write the systematic name of each organic molecule:
structure
name
П
O
☐
O
☐
O
Chapter 14 Solutions
Organic Chemistry - Standalone book
Ch. 14.3 - Prob. 1PCh. 14.3 - Prob. 2PCh. 14.4 - The 1H NMR signal for bromoform (CHBr3) appears at...Ch. 14.5 - identify the most shielded and least shielded...Ch. 14.5 - (a) Assign the chemical shifts 1.6, 2.2, and 4.8...Ch. 14.5 - Assign the chemical shifts 1.1, 1.7, 2.0, and 2.3...Ch. 14.5 - Assign the chemical shifts 1.6, 4.0, 7.5, 8.2, and...Ch. 14.6 - The 300-MHz 1H NMR spectrum of 1,4-dimethylbenzene...Ch. 14.6 - Prob. 9PCh. 14.6 - How many signals would you expect to find in the...
Ch. 14.7 - Describe the appearance of the 1H NMR spectrum of...Ch. 14.8 - Describe the appearance of the 1H NMR spectrum of...Ch. 14.11 - Prob. 13PCh. 14.11 - Prob. 14PCh. 14.12 - Hydrogen bonding between the oxygen of dimethyl...Ch. 14.14 - Prob. 16PCh. 14.15 - The 13C NMR spectrum of 1-bromo-3-chloropropane...Ch. 14.15 - Consider carbons x, y, and z in p-methylanisole....Ch. 14.15 - Prob. 19PCh. 14.16 - To which of the compounds of Problem 14.16 does...Ch. 14.18 - DEPT spectra for a compound with the formula...Ch. 14.20 - Vibrational frequencies are sensitive to isotopic...Ch. 14.21 - Prob. 23PCh. 14.22 - Prob. 24PCh. 14.23 - Prob. 25PCh. 14.23 - Which one of the C5H8 isomers shown has its max at...Ch. 14.24 - Knowing what to look for with respect to isotopic...Ch. 14.24 - The base peak appears at m/z105 for one of the...Ch. 14.24 - Mass spectra of 1-bromo-4-propylbenzene and...Ch. 14.25 - Prob. 30PCh. 14 - Each of the following compounds is characterized...Ch. 14 - Deduce the structure of each of the following...Ch. 14 - From among the isomeric compounds of molecular...Ch. 14 - The H1NMR spectrum of fluorene has signals at 3.8...Ch. 14 - Prob. 35PCh. 14 - H1NMR spectra of four isomeric alcohols with...Ch. 14 - Prob. 37PCh. 14 - We noted in Section 14.13 that an NMR spectrum is...Ch. 14 - Identify each of the C4H10O isomers on the basis...Ch. 14 - A compound (C3H7ClO2) exhibited three peaks in its...Ch. 14 - Label nonequivalent carbons in the following...Ch. 14 - Compounds A and B are isomers of molecular formula...Ch. 14 - C13 NMR spectra for four isomeric alkyl bromides...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Identify the C3H5Br isomers on the basis of the...Ch. 14 - Prob. 47PCh. 14 - A compound (C8H10O) has the IR and H1NMR spectra...Ch. 14 - Deduce the structure of a compound having the...Ch. 14 - Figure 14.53 presents IR, H1NMR, C13NMR and mass...Ch. 14 - H1NMR, C13NMR, IR, and mass spectra are shown for...Ch. 14 - 1H NMR and IR spectra for a compound with the...Ch. 14 - FriedelCraftsalkylation of benzene with...Ch. 14 - Prob. 54DSPCh. 14 - Prob. 55DSPCh. 14 - Prob. 56DSPCh. 14 - Prob. 57DSPCh. 14 - Prob. 58DSP
Knowledge Booster
Similar questions
- The 13C NMR signal for which of the indicated carbons will occur at the frequency (most deshielded)? Why is the correct answer E? Please explain what is happening. Please include a detailed explanation needed to understand the or question.arrow_forwardWhich of the following reagents best achieves the reaction shown below? Why is the correct answer B? Please explain what is happening. Please include a detailed explanation and a drawing of steps needed to understand the reaction or question.arrow_forwardWhat is the product of the following reaction sequence? Why is the correct answer D? Please explain what is happening. Please include a detailed explanation and a drawing of steps needed to understand the reaction or question.arrow_forward
- Pls help ASAParrow_forwardThe reaction of phenylmagnesium bromide (C6H5MgBr) with propanal (CH3CH2CHO)3 followed by hydrolysis yields. A. 2-phenyl-1-propanol B. 1-phenyl-1propanol C. 3-phenyl-2-propanol D. 3-phenyl-1-propanol Why is the correct answer B? Please explain what is happening. Please include a detailed explanation and/or a drawing of steps needed to understand the reaction or question.arrow_forwardWhat is the product of the reaction sequence below? Why is the correct answer D? Please explain what is happening. Please include a detailed explanation and a drawing of steps needed to understand the reaction or question. The part that is under the pen in the image is (1) CH3CHO (2) H3O+arrow_forward
- What is the missing reactant in this organic reaction? R+ OH HD CH3-CH2-CH-CH3 H A CH3 CH3-CH2-C-O-CH-CH2-CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. No answer Click anywhere to draw the first atom of your structure. ☐ : Jm +arrow_forwardDraw the major product of the following E2 reaction. Make sure you pay attention to REGIOCHEMISTRY and STEREOCHEMISTRY. Explain why this product is formed using 10 words or less for each. (a) NaH Br acetone TSO, NaH (b) acetonearrow_forward2. Circle the compound that will react SLOWER in an E2 reaction. To get credit for this question, you must EXPLAIN how you got your answer using STRUCTURES and WORDS. Br ** Br...arrow_forward
- 8. 2 20 00 Draw ALL of the possible products for the following reaction CIRCLE the MAJOR product NaOMe MeOHarrow_forwardNAME: 1. Draw the major product of the following E2 reaction. Make sure you pay attention to REGIOCHEMISTRY and STEREOCHEMISTRY. To get credit for this question, you must EXPLAIN how you got your answer using STRUCTURES and WORDS. Br NaOCH3 acetone F2 reaction To get credit for thisarrow_forward3. Reactions! Fill in the information missing below. Make sure to pay attention to REGIOCHEMISTRY and STEREOCHEMISTRY. Br2 CH3OH + 4. Mechanism! Show the complete arrow pushing mechanism, including all steps and intermediates for the following reactions. To get credit for this, you MUST show how ALL bonds are broken and formed, using arrows to show the movement of electrons. H3O+ HOarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning

Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,

Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning


Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning