The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined. Concept Introduction: The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms. The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

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Answer 1

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Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

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Answer 2

Question

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

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Answer 3

Question

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

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Answer 5

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

Answer 6

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

Answer 7

Chapter 14, Problem 54DSP

Interpretation Introduction

Interpretation:

The selection of the chemical shift values of the protons from the given ones that are associated with vinyl acetate protons is to be determined.

Concept Introduction:

The chemical equivalency of vinylic protons is dependent upon the symmetry of the molecule and the chemical nature of their neighboring atoms.

The presence of electronegative atom makes the proton more sensitive towards the applied magnetic field because in that case, the respective proton becomes de-shielded.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 14.3 - Prob. 1P Ch. 14.3 - Prob. 2P Ch. 14.4 - The 1H NMR signal for bromoform (CHBr3) appears at...Ch. 14.5 - identify the most shielded and least shielded...Ch. 14.5 - (a) Assign the chemical shifts 1.6, 2.2, and 4.8...Ch. 14.5 - Assign the chemical shifts 1.1, 1.7, 2.0, and 2.3...Ch. 14.5 - Assign the chemical shifts 1.6, 4.0, 7.5, 8.2, and...Ch. 14.6 - The 300-MHz 1H NMR spectrum of 1,4-dimethylbenzene...Ch. 14.6 - Prob. 9P Ch. 14.6 - How many signals would you expect to find in the...

Solution Summary: The author explains that the chemical equivalency of vinylic protons is dependent upon symmetry of the molecule and chemical nature of their neighboring atoms.

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Chapter 14 Solutions