Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 14.4, Problem 3P
The 1H NMR signal for bromoform (
Hz when recorded on a
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EFFICIENTS
SAMPLE READINGS
CONCENTRATIONS
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TOMATO SAUCE (REGULAR)
TOMATO (REDUCED SALT)
TOMATO SAUCE (REGULAR)
TOMATO (REDUCED SALT)
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6.274
3.898
301.7
151.2
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5.277
3.865
348.9
254.8
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5.136
3.639
193.7
85.9
605
4.655
3.041
308.6
199.6
05
5.135
3.664
339.5
241.4
0139
4.676
3.662
160.6
87.6
90148
5.086
3.677
337.7
242.5
0092
6.348
3.775
464.7
186.4
PART3
5.081
3.908
223.5
155.8
5.558
3.861
370.5
257.1
4.922
3.66
326.6
242.9
4.752
3.641
327.5
253.3
50
5.018
3.815
336.1
256.0
84
4.959
3.605
317.9
216.6
38
4.96
3.652
203.8
108.7
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5.052
3.664
329.8
239.0
17
5.043
3.767
221.9
149.7
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5.058
3.614
331.7
236.4
5.051
4.005
211.7
152.1
62
5.047
3.637
309.6
222.7
5.298
3.977
223.4
148.7
5.38
4.24
353.7
278.2
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5.033
4.044
334.6
268.7
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4.706
3.621
305.6
234.4
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4.816
3.728
340.0
262.7
16
4.828
4.496
304.3
283.2
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4.993
3.865
244.7
143.6
AVERAGE
STDEV
COUNT
95% CI Confidence Interval (mmol/L)
[Na+] (mg/100 mL)
95% Na+ Confidence Interval (mg/100 mL)
If we have two compounds: acetone (CH₃COCH₃) and acetic acid (CH₃COOH), applying heat to them produces an aldol condensation of the two compounds. If this is correct, draw the formula for the final product.
If we have two compounds: acetone (CH3COCH3)
and acetic acid (CH3COOH); if we apply heat (A),
what product(s) are obtained?
Chapter 14 Solutions
Organic Chemistry - Standalone book
Ch. 14.3 - Prob. 1PCh. 14.3 - Prob. 2PCh. 14.4 - The 1H NMR signal for bromoform (CHBr3) appears at...Ch. 14.5 - identify the most shielded and least shielded...Ch. 14.5 - (a) Assign the chemical shifts 1.6, 2.2, and 4.8...Ch. 14.5 - Assign the chemical shifts 1.1, 1.7, 2.0, and 2.3...Ch. 14.5 - Assign the chemical shifts 1.6, 4.0, 7.5, 8.2, and...Ch. 14.6 - The 300-MHz 1H NMR spectrum of 1,4-dimethylbenzene...Ch. 14.6 - Prob. 9PCh. 14.6 - How many signals would you expect to find in the...
Ch. 14.7 - Describe the appearance of the 1H NMR spectrum of...Ch. 14.8 - Describe the appearance of the 1H NMR spectrum of...Ch. 14.11 - Prob. 13PCh. 14.11 - Prob. 14PCh. 14.12 - Hydrogen bonding between the oxygen of dimethyl...Ch. 14.14 - Prob. 16PCh. 14.15 - The 13C NMR spectrum of 1-bromo-3-chloropropane...Ch. 14.15 - Consider carbons x, y, and z in p-methylanisole....Ch. 14.15 - Prob. 19PCh. 14.16 - To which of the compounds of Problem 14.16 does...Ch. 14.18 - DEPT spectra for a compound with the formula...Ch. 14.20 - Vibrational frequencies are sensitive to isotopic...Ch. 14.21 - Prob. 23PCh. 14.22 - Prob. 24PCh. 14.23 - Prob. 25PCh. 14.23 - Which one of the C5H8 isomers shown has its max at...Ch. 14.24 - Knowing what to look for with respect to isotopic...Ch. 14.24 - The base peak appears at m/z105 for one of the...Ch. 14.24 - Mass spectra of 1-bromo-4-propylbenzene and...Ch. 14.25 - Prob. 30PCh. 14 - Each of the following compounds is characterized...Ch. 14 - Deduce the structure of each of the following...Ch. 14 - From among the isomeric compounds of molecular...Ch. 14 - The H1NMR spectrum of fluorene has signals at 3.8...Ch. 14 - Prob. 35PCh. 14 - H1NMR spectra of four isomeric alcohols with...Ch. 14 - Prob. 37PCh. 14 - We noted in Section 14.13 that an NMR spectrum is...Ch. 14 - Identify each of the C4H10O isomers on the basis...Ch. 14 - A compound (C3H7ClO2) exhibited three peaks in its...Ch. 14 - Label nonequivalent carbons in the following...Ch. 14 - Compounds A and B are isomers of molecular formula...Ch. 14 - C13 NMR spectra for four isomeric alkyl bromides...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Identify the C3H5Br isomers on the basis of the...Ch. 14 - Prob. 47PCh. 14 - A compound (C8H10O) has the IR and H1NMR spectra...Ch. 14 - Deduce the structure of a compound having the...Ch. 14 - Figure 14.53 presents IR, H1NMR, C13NMR and mass...Ch. 14 - H1NMR, C13NMR, IR, and mass spectra are shown for...Ch. 14 - 1H NMR and IR spectra for a compound with the...Ch. 14 - FriedelCraftsalkylation of benzene with...Ch. 14 - Prob. 54DSPCh. 14 - Prob. 55DSPCh. 14 - Prob. 56DSPCh. 14 - Prob. 57DSPCh. 14 - Prob. 58DSP
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