General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
5th Edition
ISBN: 9780321967466
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 14, Problem 33CI
Interpretation Introduction

a)

To determine:

To find the condensed structural formula

Interpretation Introduction

b)

To determine:

To find the line – angle structural formula

Interpretation Introduction

c)

To determine:

To find the IUPAC name of butyraldehyde

Interpretation Introduction

d)

To determine:

To find the condensed structural formula

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2. Consider the data below to answer the following questions. Cyanohydrins are important intermediates in the synthesis of α-hydroxycarboxylic acids from ketones and aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid. Nitriles can also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. OH CH-COOH 0 HO CN C H30* C. H H HC N NaOH H₂O C=O 0 cyanohydrin H + NaCN + H₂O
Assign all integrated peaks
- Consider the data in the Table below to answer the following questions: Acidities of Substituted Benzoic and Acetic Acids pk,s at 25C Y-CH COOH Y Y - CH₂COOH meta para H 4.75 4.19 4.19 2.47 3.64 3.55 3.57 4.09 4.46 CN OCH 3 A. Draw the structure of the strongest acid in the table above. B. Explain why cyanoacetic acid and methoxyacetic acid are more acidic than their correspondingly substituted benzoic acid counterparts.

Chapter 14 Solutions

General, Organic, and Biological Chemistry: Structures of Life (5th Edition)

Ch. 14.1 - Prob. 14.11QAPCh. 14.1 - Prob. 14.12QAPCh. 14.2 - Prob. 14.13QAPCh. 14.2 - Prob. 14.14QAPCh. 14.2 - Prob. 14.15QAPCh. 14.2 - Prob. 14.16QAPCh. 14.2 - Prob. 14.17QAPCh. 14.2 - Prob. 14.18QAPCh. 14.3 - Prob. 14.19QAPCh. 14.3 - Prob. 14.20QAPCh. 14.3 - Prob. 14.21QAPCh. 14.3 - Prob. 14.22QAPCh. 14.3 - Prob. 14.23QAPCh. 14.3 - Prob. 14.24QAPCh. 14.4 - Prob. 14.25QAPCh. 14.4 - Prob. 14.26QAPCh. 14.4 - Prob. 14.27QAPCh. 14.4 - Prob. 14.28QAPCh. 14.4 - Prob. 14.29QAPCh. 14.4 - Prob. 14.30QAPCh. 14.5 - Prob. 14.31QAPCh. 14.5 - Prob. 14.32QAPCh. 14.5 - Prob. 14.33QAPCh. 14.5 - Prob. 14.34QAPCh. 14.5 - Prob. 14.35QAPCh. 14.5 - Prob. 14.36QAPCh. 14.5 - Prob. 14.37QAPCh. 14.5 - Prob. 14.38QAPCh. 14.5 - Prob. 14.39QAPCh. 14.5 - Prob. 14.40QAPCh. 14.5 - Prob. 14.41QAPCh. 14.5 - Prob. 14.42QAPCh. 14 - Prob. 14.43UTCCh. 14 - The compound frambinone has the taste of...Ch. 14 - Prob. 14.45UTCCh. 14 - Prob. 14.46UTCCh. 14 - Prob. 14.47UTCCh. 14 - Prob. 14.48UTCCh. 14 - Prob. 14.49UTCCh. 14 - Prob. 14.50UTCCh. 14 - Prob. 14.51AQAPCh. 14 - Prob. 14.52AQAPCh. 14 - Prob. 14.53AQAPCh. 14 - Prob. 14.54AQAPCh. 14 - Prob. 14.55AQAPCh. 14 - Prob. 14.56AQAPCh. 14 - Prob. 14.57AQAPCh. 14 - Prob. 14.58AQAPCh. 14 - Prob. 14.59AQAPCh. 14 - Prob. 14.60AQAPCh. 14 - Prob. 14.61AQAPCh. 14 - Prob. 14.62AQAPCh. 14 - Prob. 14.63AQAPCh. 14 - Prob. 14.64AQAPCh. 14 - Prob. 14.65AQAPCh. 14 - Prob. 14.66AQAPCh. 14 - Prob. 14.67AQAPCh. 14 - Prob. 14.68AQAPCh. 14 - Prob. 14.69AQAPCh. 14 - Prob. 14.70AQAPCh. 14 - Prob. 14.71CQCh. 14 - Prob. 14.72CQCh. 14 - Prob. 14.73CQCh. 14 - Prob. 14.74CQCh. 14 - Prob. 14.75CQCh. 14 - Prob. 14.76CQCh. 14 - Prob. 14.77CQCh. 14 - Prob. 14.78CQCh. 14 - A compound called butylated hydroxytoluene, or...Ch. 14 - Prob. 28CICh. 14 - Prob. 29CICh. 14 - Prob. 30CICh. 14 - Prob. 31CICh. 14 - Cl.32 lonone is a compound that gives sweet...Ch. 14 - Prob. 33CICh. 14 - Prob. 34CI
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