Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 14, Problem 31E
Explain why the ionization constant, Ka, for H2SO4 is larger than the ionization constant for H2SO3.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Explain why the ionization constant, Ka, for H2SO4 is larger than the ionization constant for H2SO3.
Acid Structure and Relative Acidity
The strength of an acid, HA, is often determined by the strength and polarity of the H-A
bond. In general, a weaker and more polar bond leads to a stronger acid.
For binary acids of elements in the same group of the periodic table, the H-A bond
strength decreases down the group, so acidity increases.
For binary acids of elements in the same row of the periodic table, the polarity of the H-A
bond increases from left to right (as the electronegativity of A increases), so acid strength
increases.
For oxoacids, acid strength increases with the oxidation number of the central atom. If the
oxidation number is the same, acid strength increases with the electronegativity of the
central atom.
Part A
Rank the following compounds in order decreasing acid strength using periodic trends.
Rank the acid strength from strongest to weakest. To rank items as equivalent, overlap them.
▸ View Available Hint(s)
BH₁ HBr HCI H₂S
Greatest acid strength
The correct ranking…
Classify the compounds below as acid, base, salt or oxide of Na₂O
Chapter 14 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 14 - Write equations that show NH3 as both a conjugate...Ch. 14 - Write equations that show H2PO4- acting both as an...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - Show by suitable net ionic equations that each of...Ch. 14 - What is the conjugate acid of each of the...Ch. 14 - What is the conjugate acid of each of the...Ch. 14 - Identify and label the Bronsted-Lowry acid, its...Ch. 14 - Identify and label the Bronsted-Lowry acid, its...
Ch. 14 - What are amphiprotic species? Illustrate with...Ch. 14 - State which of the following species are...Ch. 14 - State which of the following species are...Ch. 14 - Is the self-ionization of water endothermic or...Ch. 14 - Explain why a sample of pure water at 40 C is...Ch. 14 - The ionization constant for water (Kw) is 2.91014...Ch. 14 - The ionization constant for water (Kw) is...Ch. 14 - Calculate the pH and the pOH of each of the...Ch. 14 - Calculate the pH and the pOH of each of the...Ch. 14 - What are the pH and pOH of a solution of 2.0 M...Ch. 14 - What are the hydronium and hydroxide ion...Ch. 14 - Calculate the hydrogen ion concentration and the...Ch. 14 - Calculate the hydronium ion concentration and the...Ch. 14 - The hydronium ion concentration in a sample of...Ch. 14 - The hydroxide ion concentration in household...Ch. 14 - Explain why the neutralization reaction of a...Ch. 14 - Explain why the neutralization reaction of a weak...Ch. 14 - Use this list of important industrial compounds...Ch. 14 - The odor of vinegar is due to the presence of...Ch. 14 - Household ammonia is a solution of the weak base...Ch. 14 - Explain why the ionization constant, Ka, for H2SO4...Ch. 14 - Explain why the ionization constant, Ka, for HI is...Ch. 14 - Gastric juice, the digestive ?uid produced in the...Ch. 14 - Nitric acid reacts with insoluble copper (II)...Ch. 14 - What is the ionization constant at 25 C for the...Ch. 14 - What is the ionization constant at 25 C for the...Ch. 14 - Which base, CH3NH2 or (CH3)2NH, is the stronger...Ch. 14 - Which is the stronger acid, NH4+ or HBrO?Ch. 14 - Which is the stronger base, (CH3)3N or H2BO3-?Ch. 14 - Predict which acid in each of the following pairs...Ch. 14 - Predict which compound in each of the following...Ch. 14 - Rank the compounds in each of the following groups...Ch. 14 - Rank the compounds in each of the following groups...Ch. 14 - Both HF and HCN ionize in water to a limited...Ch. 14 - The active ingredient formed by aspirin in the...Ch. 14 - What do we represent when we write:...Ch. 14 - Explain why equilibrium calculations are not...Ch. 14 - Are the concentrations of hydronium ion and...Ch. 14 - What two common assumptions can simplify...Ch. 14 - What two common assumptions can simplify...Ch. 14 - Which of the following will increase the percent...Ch. 14 - Which of the following will increase the percent...Ch. 14 - What is the effect on the concentrations of NO2-,...Ch. 14 - What is the effect on the concentration of...Ch. 14 - Why is the hydronium ion concentration in a...Ch. 14 - From the equilibrium concentrations given,...Ch. 14 - From the equilibrium concentrations given,...Ch. 14 - Determine Kb for the nitrite ion, NO2-. In a...Ch. 14 - Determine Ka for hydrogen sulfate ion, HSO4-. In a...Ch. 14 - Calculate the ionization constant for each of the...Ch. 14 - Calculate the ionization constant for each of the...Ch. 14 - For which of the following solutions must we...Ch. 14 - Even though both NH3 and C6H5NH2 are weak bases,...Ch. 14 - Calculate the equilibrium concentration of the...Ch. 14 - Calculate the equilibrium concentration of the...Ch. 14 - Calculate the equilibrium concentration of the...Ch. 14 - Calculate the equilibrium concentration of the...Ch. 14 - Using the Ka value of , place Al(H2O)63+ in the...Ch. 14 - Calculate the concentration of all solute species...Ch. 14 - Propionic acid, C2H5CO2H (Ka=1.34105), is used in...Ch. 14 - White vinegar is a 5.0% by mass solution of acetic...Ch. 14 - The ionization constant of lactic acid,...Ch. 14 - Nicotine, C10H14N2, is a base that will accept two...Ch. 14 - The pH of a 0.20-M solution of HP is 1.92....Ch. 14 - The pH of a 0.15-M solution of HSO4- is 1.43....Ch. 14 - The pH of a 0.10-M solution of caffeine is 11.16....Ch. 14 - Tile pH of a solution of household ammonia, a...Ch. 14 - Determine whether aqueous solutions of the...Ch. 14 - Determine whether aqueous solutions of the...Ch. 14 - Novocaine, C13H21O2N2Cl, is the salt of the base...Ch. 14 - Which of the following concentrations would be...Ch. 14 - Calculate the concentration of each species...Ch. 14 - Calculate the concentration of each species...Ch. 14 - Salicylic acid, HOC6H4CO2H, and its derivatives...Ch. 14 - The ion HTe- is an amphiprotic species; it can act...Ch. 14 - Explain why a buffer can be prepared from a...Ch. 14 - Explain why the pH does not change significantly...Ch. 14 - Explain why the pH does not change significantly...Ch. 14 - What is [H3O+] in a solution of 0.25 M CH3CO2H and...Ch. 14 - What is [H3O+] in a solution of 0.075 M HNO2 and...Ch. 14 - What is [OH-] in a solution of 0.125 M CH3NH2 and...Ch. 14 - What is [OH-] in a solution of 1.25 M NH3 and 0.78...Ch. 14 - What concentration of NH4NO3 is required to make...Ch. 14 - What concentration of NaF is required to make...Ch. 14 - What is the effect on the concentration of acetic...Ch. 14 - What is the effect on the concentration of...Ch. 14 - What will be the pH of a buffer solution prepared...Ch. 14 - Calculate the pH of a buffer solution prepared...Ch. 14 - How much solid NaCH3CO23H2O must be added to 0300...Ch. 14 - What mass of NH4Cl must be added to 0.750 L of a...Ch. 14 - A buffer solution is prepared from equal volumes...Ch. 14 - A 5.36-g sample of NH4Cl was added to 25.0 mL of...Ch. 14 - Which acid in Table 14.2 is most appropriate for...Ch. 14 - Which acid in Table 14.2 is most appropriate for...Ch. 14 - Which base in Table 14.3 is must appropriate for...Ch. 14 - Which base in Table 14.3 is most appropriate for...Ch. 14 - Saccharin, C7H4NSO3H, is a weak acid (Ka=2.1102)....Ch. 14 - What is the pH of 1.000 L of a solution of 100.0 g...Ch. 14 - Explain how to choose the appropriate acid-base...Ch. 14 - Explain why an acid-base indicator changes color...Ch. 14 - Why can we ignore the contribution of water to the...Ch. 14 - Why can we ignore the contribution of water to the...Ch. 14 - Draw a curve for a series of solutions of HF. Plot...Ch. 14 - Draw a curve similar to that shown in Figure 14.23...Ch. 14 - Calculate the pH at the following points in a...Ch. 14 - The indicator dinitrophenol is an acid with a Ka...
Additional Science Textbook Solutions
Find more solutions based on key concepts
Repeat Exercise 9.24 for the pulley shown in Figure 9.26(c), assuming you pull straight up on the rope. The pul...
College Physics
1. Why is the quantum-mechanical model of the atom important for understanding chemistry?
Chemistry: Structure and Properties
Without looking at the structures, give molecular formulas for the compounds in Problem 3-8 (a) and (b). Use th...
Organic Chemistry (9th Edition)
49. A 25.00-mL sample of an solution of unknown concentration is titrated with a 0.1322 M KOH solution. A volu...
Introductory Chemistry (6th Edition)
Consider a galvanic cell that uses the following half-reactions: 2H+(aq)+2eH2(g)Al3+(aq)+3eAl(s) a) What materi...
CHEMISTRY-TEXT
Draw the mechanism for the reaction of cyclohexene with HCl.
Organic Chemistry (8th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Arsenic acid, H3AsO4, has a pkai = 2.22. What is the value of Kal?arrow_forwardWhich reaction below represents the second ionization of Sr? Sr(g) → Sr+(g) + e- Sr2+(g) + e- → Sr+(g) Sr+(g) → Sr2+(g) + e- Sr+(g) + e- → Sr(g) Sr-(g) + e- → Sr2-(g)arrow_forwardA baker uses sodium hydrogen carbonate (baking soda) asthe leavening agent in a banana-nut quickbread. The baking sodadecomposes according to two possible reactions: 2NaHCO₃(s)→Na₂CO₃(s)+CO₂(g)+H₂O(l) , NaHCO₃(s)+H⁺(aq)→Na⁺(aq)+CO₂(g)+H₂O(l) Calculate the volume (in mL) of CO₂ that forms at 200°C and0.975 atm per gram of NaHCO₃ by each of the reaction processes.arrow_forward
- Use polarity and bond strength arguments to explain why HF is a stronger acid than H2O.arrow_forwardWrite an equation to show that hypochlorous acid , HClO , behaves as an acid in water. + H2O = +arrow_forwardWhich of the following ionizes to the greatest extent? Multiple Choice HCO2H, Ka = 1.8 × 10−4 HNO2, Ka = 5.6 × 10−4 NH4+, KKa = 5.6 × 10−10 CH3CO2H, Ka = 1.8 × 10−5 HCN, Ka = 6.2 × 10−10arrow_forward
- Write the formula of the acid formed when each of these acidic oxides reacts with water. 1. Cl20, 2. О2F2 3. 1409 4. NOarrow_forwardWrite equations showing the stepwise ionization of phosphorous acid.arrow_forwardDescribe the following giving one example for each :(i) Detergents(ii) Food preservatives(iii) Antacidsarrow_forward
- At each altitude, the ionized atomic oxygen (O+) density sometimes approaches, but never exceeds the electron density (e-). Explain why O+ density does not exceed electron density.arrow_forwardRank the following according to increasing acidity of the hydrogen atom. HO, OH II II O I> III > || O I>|| > II III>I>|| O III > I|>Iarrow_forwardWhich equation correctly represents the first ionization of calcium? A Са+ (g) + e- Ca (g) Са- (g) Са (g) + e- Са (g) — Са-(g) + е- Са (g) Са+ (g) + e- E Са (g) + e- — Са-(g)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY