Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 1.4, Problem 16P
(a)
Interpretation Introduction
Interpretation:
The condensed structure should be drawn for the given compound or model.
Concept introduction:
- Condensed structure: A structure that does not show some (or all) of the covalent bonds.
- When the atom is neutral, Carbon form 2 bond, Nitrogen forms 3 bonds Oxygen forms 2 bonds and Hydrogen or a Halogen forms 1 bond.
- A carbocation has a positively charge carbon, a carbanion has a negatively charge carbon and a radical has an unpaired electron.
(b)
Interpretation Introduction
Interpretation:
The condensed structure should be drawn for the given compound or model.
Concept introduction:
- Condensed structure: A structure that does not show some (or all) of the covalent bonds.
- When the atom is neutral, C form 2 bonds, N forms 3 bonds O forms 2 bonds and H or a halogen forms 1 bond.
- A carbocation has a positively charge carbon, a carbon has a negatively charge carbon and a radical has an unpaired electron.
(c)
Interpretation Introduction
Interpretation:
The condensed structure should be drawn for the given compound or model.
Concept introduction:
- Condensed structure: A structure that does not show some (or all) of the covalent bonds.
- When the atom is neutral, C form 2 bonds, N forms 3 bonds O forms 2 bonds and H or a halogen forms 1 bond.
- A carbocation has a positively charge carbon, a carbon has a negatively charge carbon and a radical has an unpaired electron.
(d)
Interpretation Introduction
Interpretation:
The condensed structure should be drawn for the given compound or model.
Concept introduction:
- Condensed structure: A structure that does not show some (or all) of the covalent bonds.
- When the atom is neutral, C form 2 bonds, N forms 3 bonds O forms 2 bonds and H or a halogen forms 1 bond.
- A carbocation has a positively charge carbon, a carbon has a negatively charge carbon and a radical has an unpaired electron.
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1.2
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The distance the light travels is different
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5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo-
hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number
of significant figures.
B. Freezing Point of Cyclohexane plus
Calculation Zone
Unknown Solute
2. Mass of cyclohexane (g)
10.14
Part C.4
3. Mass of added solute (g)
0.255
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1. k; for cyclohexane (°C⚫ kg/mol)
20.0
2. Freezing point change, AT, (°C)
3.04
Part C.6
3. Mass of cyclohexane in solution (kg)
4. Moles of solute, total (mol)
Show calculation.
5. Mass of solute in solution, total (g)
6. Molar mass of solute (g/mol)
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Chapter 1 Solutions
Essential Organic Chemistry, Global Edition
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.2 - Prob. 2PCh. 1.2 - How many valence electrons do chlorine, bromine,...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar?Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...
Ch. 1.4 - Prob. 12PCh. 1.4 - a. Draw two Lewis structures for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 16PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 18PCh. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.9 - Put a number in each of the blanks: a. ___ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 25PCh. 1.13 - a. Predict the relative lengths and strengths of...Ch. 1.13 - Prob. 28PCh. 1.14 - Which of the bonds in a carbonoxygen double bond...Ch. 1.14 - Caffeine is a natural insecticide, found in the...Ch. 1.14 - a. What is the hybridization of each of the carbon...Ch. 1.14 - Prob. 33PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Account for the difference in the shape and color...Ch. 1.15 - Which of the following molecules would you expect...Ch. 1 - Draw a Lewis structure for each of the following...Ch. 1 - Prob. 38PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Prob. 40PCh. 1 - Draw the condensed structure of a compound that...Ch. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Draw a Lewis structure for each of the following...Ch. 1 - Prob. 45PCh. 1 - List the bonds in order from most polar to least...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Write the Kekul structure for each of the...Ch. 1 - Assign the missing formal charges.Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 51PCh. 1 - a. Which of the indicated bonds in each compound...Ch. 1 - In which orbitals are the lone pairs in nicotine?...Ch. 1 - Draw the missing lone-pair electrons and assign...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - Prob. 56PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 58PCh. 1 - Sodium methoxide (CH3ONa) has both ionic and...Ch. 1 - a. Why is a H 8 H bond (0.74 ) shorter than a C 8...Ch. 1 - Which compound has a larger dipole moment, CHCl3...Ch. 1 - Which compound has a longer C 8 Cl bond?Ch. 1 - Prob. 63PCh. 1 - The following compound has two isomers. One isomer...
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