EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
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Chapter 14, Problem 14.8P

(a)

Interpretation Introduction

Interpretation:

Diagram of cell has to be drawn.

Concept Introduction:

Redox reaction is reaction that includes change in oxidation number of molecule, atom or ion and this changes are due to transfer of electron from one species to another. A complete reaction involves oxidation and reduction. Cell potential is evaluated by expression as follows:

  Ecell°=Eoxidation°+Ereduction°

(b)

Interpretation Introduction

Interpretation:

Half-reaction for the each half cell has to be written.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Direction of electron flow, identification of cathode and anode and overall cell reaction has to be written.

Concept Introduction:

Refer to part (a).

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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