EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 14, Problem 14.11P

(a)

Interpretation Introduction

Interpretation:

Line notation for indicated cell has to be written.

Concept Introduction:

Cell that is more negatively charge has better oxidation tendency and thus will readily lose electron. Electrons released from this electrode will reach the positive reduction potential electrode. For a general representation, the oxidation half cell is drawn in left separated by double vertical parallel lines while reduction half cell comes at right.

(b)

Interpretation Introduction

Interpretation:

Cell potential for each half reaction has to be found and net cell voltage has to be calculated.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Cell-diagram has to be drawn. Also, electrode that acts as anode when salt bridge is incorporated has to be identified.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Spontaneous net cell reaction has to be written.

Concept Introduction:

Refer to part (d).

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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