Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 14, Problem 14.48P
Cracking propane is a route to light olefin production. Suppose that two cracking reactions occur in a steady-flow reactor.
Calculate the product composition if both reactions go to equilibrium at 1.2 bar and
(a) 750 K; (b) 1000 K; (c) 1250 K
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
A mixture of oil and gas flows through a horizontal pipe with an
inside diameter of 150 mm. The respective volumetric flow rates for
the oil and gas are 0.015 and 0.29 m³s-1. Determine the gas void frac-
tion and the average velocities of the oil and gas. The friction factor
may be assumed to be 0.0045. The gas has a density of 2.4 kgm³ and
viscosity of 1 x 10-5 Nsm-2. The oil has a density of 810 kgm³ and
density of 0.82 Nsm². Answer: 0.79, 20.8 ms-1, 4 ms-1
4. An experimental test rig is used to examine two-phase flow regimes
in horizontal pipelines. A particular experiment involved uses air
and water at a temperature of 25°C, which flow through a horizontal
glass tube with an internal diameter of 25.4 mm and a length of 40 m.
Water is admitted at a controlled rate of 0.026 kgs at one end and air
at a rate of 5 x 104 kgs in the same direction. The density of water
is 1000 kgm³, and the density of air is 1.2 kgm3. Determine the mass
flow rate, the mean density, gas void fraction, and the superficial
velocities of the air and water. Answer: 0.02605 kgs 1, 61.1 kgm³, 0.94,
0.822 ms-1, 0.051 ms-1
1. Determine the range of mean density of a mixture of air in a 50:50
oil-water liquid phase across a range of gas void fractions. The den-
sity of oil is 900 kgm³, water is 1000 kgm³, and gas is 10 kgm³.
2. Describe, with the use of sketches, the various flow regimes that can
exist in a vertical pipe carrying two-phase flow (liquid and gas).
Chapter 14 Solutions
Introduction to Chemical Engineering Thermodynamics
Ch. 14 - Prob. 14.1PCh. 14 - A system initially containing 2 mol C2H4 and 3 mol...Ch. 14 - A system formed initially of 2 mol CO2 , 5 mol H2...Ch. 14 - Consider the water-gas-shift reaction:...Ch. 14 - Rework Prob. 14.4 for a temperature of: (a) HOOK:...Ch. 14 - Use the method of equilibrium constants to verify...Ch. 14 - Prob. 14.7PCh. 14 - For ideal gases, exact mathematical expressions...Ch. 14 - For the ammonia synthesis reaction written:...Ch. 14 - Peter. Paul, and Mary, members of a thermodynamics...
Ch. 14 - The following reaction reaches equilibrium at...Ch. 14 - The following reaction reaches equilibrium at...Ch. 14 - The following reaction reaches equilibrium at...Ch. 14 - The following reaction, hydrogenation of styrene...Ch. 14 - The gas stream from a sulfur burner is composed of...Ch. 14 - Prob. 14.16PCh. 14 - Ethylene is produced by the dehydrogenation of...Ch. 14 - The production of 1,3-butadiene can be carried out...Ch. 14 - The production of 1,3-butadiene can be carried out...Ch. 14 - For the ammonia synthesis reaction, 12N2g+32H2NH3g...Ch. 14 - Prob. 14.21PCh. 14 - Prob. 14.22PCh. 14 - Ammonium chloride NH4Cls decomposes upon heating...Ch. 14 - A chemically reactive system contains the...Ch. 14 - The relative compositions of the pollutants NO and...Ch. 14 - Carbon black is produced by the decomposition of...Ch. 14 - Consider the reactions 12N2g+12O2gNOg12N2g+O2gNO2g...Ch. 14 - Oil refineries often have both H2S and SO2 to...Ch. 14 - Species N2O4 and NO2 as gases come to equilibrium...Ch. 14 - The following isomerization reaction occurs in the...Ch. 14 - Prob. 14.32PCh. 14 - The feed gas to a methanol synthesis reactor is...Ch. 14 - Prob. 14.34PCh. 14 - Consider the gas-phase isomerization reaction: ....Ch. 14 - A low-pressure, gas-phase isomerization reaction,...Ch. 14 - Set up the equations required for solution of Ex....Ch. 14 - Reaction-equilibrium calculations may be useful...Ch. 14 - Ethylene oxide as a vapor and water as liquid,...Ch. 14 - In chemical-reaction engineering, special measures...Ch. 14 - The following problems involving chemical-reaction...Ch. 14 - The following is an industrial-safety rule of...Ch. 14 - Prob. 14.43PCh. 14 - The standard heat of reaction A/f3 for gas-phase...Ch. 14 - Ethanol is produced from ethylene via the...Ch. 14 - A good source for formation data for compounds is...Ch. 14 - Reagent-grade, liquid-phase chemicals often...Ch. 14 - Cracking propane is a route to light olefin...Ch. 14 - Equilibrium at 425 K and 15 bar is established for...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.Similar questions
- A mixture of high pressure water and steam at a rate of 0.5 kgs-¹ flows up a vertical tube with an inside diameter of 25.4 mm at a pres- sure 22 bar. Determine the type of flow if the mass quality is 1%. The density of the water is 845 kgm³, the density of steam is 10.8 kgm³, and the viscosity of the water is 1.24 x 104 Nsm2. Answer: Slug flowarrow_forward5. Describe, with the use of sketches, the various two-phase flow regimes that can exist in a horizontal pipe carrying a liquid and a gas. 6. Explain what is meant by gas hold-up and describe ways in which it can be measured.arrow_forwardA mixture of air and water at a temperature of 25°C flows up through a vertical tube with a length of 4 m and an internal diameter of 25.4 mm with the exit of the tube being at atmospheric pressure. The mass flows of the air and the water are 0.007 kgs¹ and 0.3 kgs-¹, respectively. For air, the density is 1.2 kgm3 and viscosity is 1.85 x 10-5 Nsm-2, and for water, the density is 1000 kgm-3 and viscosity is 8.9 × 10-4 Nsm 2. Answer: 2.7 kNm 2marrow_forward
- At a Pressure of 200 mm Hg, match the substance with the boiling temperature. 69.50°C 1. Benzene 1.92°C 2. Toluene 41.94°C 3. n-Pentane 4. n-Hexane 31.61°Carrow_forwardAt a Pressure of 400 mm Hg, match the substance with the boiling temperature. 62.89°C 1. Styrene 122.69°C 2. Ethanol 3. Toluene 89.48°C 4. Benzene 60.61°Carrow_forward8. A gas is admitted at a rate of 0.015 m³s-¹ to a vertical glass pipe with an inside diameter of 50 mm. The gas bubbles that form travel with a velocity of 32 ms-¹. Determine the gas void fraction and the velocity of the liquid if the volumetric flow is 2.5 x 10-5 m³s-1. Answer: 0.24, 1.7 ms-1 9 Characterise the main concepts of a homogeneous flow model sepa-arrow_forward
- 3. A mixture of air and water at a temperature of 25°C flows up through a vertical tube with a length of 4 m and an internal diameter of 25.4 mm with the exit of the tube being at atmospheric pressure. The mass flows of the air and the water are 0.007 kgs-1 and 0.3 kgs-1, respectively. For air, the density is 1.2 kgm³ and viscosity is 1.85 x 10-5 Nsm-2, and for water, the density is 1000 kgm-3 and viscosity is 8.9 × 10-4 Nsm-2. Answer: 2.7 kNm-2m-1arrow_forward15. Show that for a one-dimensional annular flow in a horizontal pipe with no acceleration, the pressure gradient on the gas core is dp= 4ti dz d√√α where t, is the interfacial shear stress and a is the gas void fraction.arrow_forwarda gas. Problems in Two phase flow docx horizontal pipe carrying a liquid and that can exist in 6. Explain what is meant by gas hold-up and describe ways in which it can be measured. Ets required to transporta ydrocarbon as a two-phase mixture ofarrow_forward
- 7. It is required to transport a hydrocarbon as a two-phase mixture of liquid and vapour along a smooth-walled pipe with an inside diam- eter of 100 mm. The total hydrocarbon flow rate is 2.4 kgs-1 with a vapour mass fraction of 0.085. The pipe is to operate at an absolute pressure of 2.2 bar. The liquid density is 720 kgm³, and viscosity is 4.8 × 10-4 Nsm², while for the vapour, the density is 1.63 kgm³, and the viscosity is 2.7 x 10-5 Nsm-2. Determine the maximum per- missible length of pipe if the pressure drop along the pipe is not to exceed 20 kNm-2. Answer: 44 marrow_forward13. Show that the gas void fraction for a flowing gas-liquid mixture can be expressed in terms of the phase velocity, quality, and densities of the mixture as 1 α = PU (1-x) 1+18 Բ. Ա. xarrow_forwardvelocis the air and water. Answer: 0.02605 kgs-1, 61.1 kgm 3, 0.94, 0.822 ms-1, 0.051 ms-1 5. Describe, with the use of sketches, the various two-phase flow regimes that can exist in a horizontal pipe carrying a liquid and a gas. 6. Explate what is mean by gas hold up and describe way which itarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami...Chemical EngineeringISBN:9781259696527Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark SwihartPublisher:McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind...Chemical EngineeringISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Elements of Chemical Reaction Engineering (5th Ed...Chemical EngineeringISBN:9780133887518Author:H. Scott FoglerPublisher:Prentice Hall
Industrial Plastics: Theory and ApplicationsChemical EngineeringISBN:9781285061238Author:Lokensgard, ErikPublisher:Delmar Cengage Learning
Unit Operations of Chemical EngineeringChemical EngineeringISBN:9780072848236Author:Warren McCabe, Julian C. Smith, Peter HarriottPublisher:McGraw-Hill Companies, The
Introduction to Chemical Engineering Thermodynami...
Chemical Engineering
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind...
Chemical Engineering
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Elements of Chemical Reaction Engineering (5th Ed...
Chemical Engineering
ISBN:9780133887518
Author:H. Scott Fogler
Publisher:Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:9781285061238
Author:Lokensgard, Erik
Publisher:Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:9780072848236
Author:Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:McGraw-Hill Companies, The
Chemical Equilibria and Reaction Quotients; Author: Professor Dave Explains;https://www.youtube.com/watch?v=1GiZzCzmO5Q;License: Standard YouTube License, CC-BY
Chemical Equilibrium Constant K - Ice Tables - Kp and Kc; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=J4WJCYpTYj8;License: Standard Youtube License