The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given. Concept Introduction: Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

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Answer 1

Question

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol. Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf

Predict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2

When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.

Answer 2

Question

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

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Answer 3

Question

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

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Answer 4

Question

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

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Answer 5

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

Answer 6

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

Answer 7

Chapter 14, Problem 14.11QP

Interpretation Introduction

Interpretation:

The explanation why a carboxylic acid has more polar nature and higher boiling point than an alcohol or an aldehyde has to be given.

Concept Introduction:

Carboxylic acid consists of carboxyl group. A carboxyl group is a functional group consisting of carbonyl group (C=O) with hydroxyl group (O-H) attached to the same carbon atom. Carboxylic acids are used as precursors to form other compounds such as esters, aldehydes and ketones.

Answer 8

Expert Solution & Answer

Explanation of Solution

The functional group present in carboxylic acids is carboxyl group (-COOH). Carboxylic acids can exhibit hydrogen bonding with themselves. Carboxylic acids have the ability to form a dimer by hydrogen bonding that enables a stable arrangement. Since the carboxyl group is polar and intermolecular hydrogen bonds is formed with one another in carboxylic acids, and they tend to have strong dipole-dipole attraction. Hence, carboxylic acids are more polar nature and have higher boiling points than an alcohol or an aldehyde.

Answer 9

Expert Solution & Answer

Answer 10

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Answer 11

Ch. 14.1 - Assuming that each of the following pairs of...Ch. 14.1 - Assuming that each of the following pairs of...Ch. 14.1 - Prob. 14.3Q Ch. 14.1 - Why would you predict that a carboxylic acid would...Ch. 14.1 - Prob. 14.1PP Ch. 14.1 - Prob. 14.5Q Ch. 14.1 - Prob. 14.6Q Ch. 14.1 - Prob. 14.2PP Ch. 14.1 - Prob. 14.3PP Ch. 14.1 - Prob. 14.4PP

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Chapter 14 Solutions