The unbranched 1-alkene that will be liquid at room temperature has to be chosen from the given set of options. Concept Introduction: Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula. Alkenes are linear chain unsaturated hydrocarbons and cycloalkenes are cyclic carbon chain unsaturated hydrocarbons. They both occur naturally. Alkenes and cycloalkenes are hydrocarbons. They are nonpolar molecules. Water is a polar molecule. Therefore, alkenes and cycloalkenes do not get solubilized in water. In other words, alkenes and cycloalkenes are insoluble in water. Regarding density, alkenes and cycloalkenes have density lower than water. When alkenes and cycloalkenes are mixed with water, two layers are formed which is a result of insolubility. Alkenes and cycloalkenes are present on top of water layer which is due to lesser density. Boiling point of alkenes and cycloalkenes increase with an increase in carbon‑chain length or the ring size. The continuous chain alkenes which contain two to four carbon atoms are gases at room temperature. The continuous chain alkenes that contain five to seventeen carbon atoms and one double bond are liquids at room temperature. When branching happens in the carbon chain, it lowers the boiling point of alkenes. In simple words, unbranched alkenes have more boiling point than branched alkenes with the same number of carbon atoms. Cycloalkenes have more boiling point compared to noncyclic alkenes with the same number of carbon atoms. This is due to the more rigid and more symmetrical structures that occur in cyclic systems. Cyclopropene and cyclobutene are relatively unstable compound and gets converted into other hydrocarbons.

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Answer 1

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13.8, Problem 2QQ

Interpretation Introduction

Interpretation:

The unbranched 1-alkene that will be liquid at room temperature has to be chosen from the given set of options.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkenes are linear chain unsaturated hydrocarbons and cycloalkenes are cyclic carbon chain unsaturated hydrocarbons. They both occur naturally.

Alkenes and cycloalkenes are hydrocarbons. They are nonpolar molecules. Water is a polar molecule. Therefore, alkenes and cycloalkenes do not get solubilized in water. In other words, alkenes and cycloalkenes are insoluble in water.

Regarding density, alkenes and cycloalkenes have density lower than water. When alkenes and cycloalkenes are mixed with water, two layers are formed which is a result of insolubility. Alkenes and cycloalkenes are present on top of water layer which is due to lesser density.

Boiling point of alkenes and cycloalkenes increase with an increase in carbon‑chain length or the ring size. The continuous chain alkenes which contain two to four carbon atoms are gases at room temperature. The continuous chain alkenes that contain five to seventeen carbon atoms and one double bond are liquids at room temperature.

When branching happens in the carbon chain, it lowers the boiling point of alkenes. In simple words, unbranched alkenes have more boiling point than branched alkenes with the same number of carbon atoms.

Cycloalkenes have more boiling point compared to noncyclic alkenes with the same number of carbon atoms. This is due to the more rigid and more symmetrical structures that occur in cyclic systems. Cyclopropene and cyclobutene are relatively unstable compound and gets converted into other hydrocarbons.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13.8, Problem 2QQ

Interpretation Introduction

Interpretation:

The unbranched 1-alkene that will be liquid at room temperature has to be chosen from the given set of options.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkenes are linear chain unsaturated hydrocarbons and cycloalkenes are cyclic carbon chain unsaturated hydrocarbons. They both occur naturally.

Alkenes and cycloalkenes are hydrocarbons. They are nonpolar molecules. Water is a polar molecule. Therefore, alkenes and cycloalkenes do not get solubilized in water. In other words, alkenes and cycloalkenes are insoluble in water.

Regarding density, alkenes and cycloalkenes have density lower than water. When alkenes and cycloalkenes are mixed with water, two layers are formed which is a result of insolubility. Alkenes and cycloalkenes are present on top of water layer which is due to lesser density.

Boiling point of alkenes and cycloalkenes increase with an increase in carbon‑chain length or the ring size. The continuous chain alkenes which contain two to four carbon atoms are gases at room temperature. The continuous chain alkenes that contain five to seventeen carbon atoms and one double bond are liquids at room temperature.

When branching happens in the carbon chain, it lowers the boiling point of alkenes. In simple words, unbranched alkenes have more boiling point than branched alkenes with the same number of carbon atoms.

Cycloalkenes have more boiling point compared to noncyclic alkenes with the same number of carbon atoms. This is due to the more rigid and more symmetrical structures that occur in cyclic systems. Cyclopropene and cyclobutene are relatively unstable compound and gets converted into other hydrocarbons.

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Answer 3

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13.8, Problem 2QQ

Interpretation Introduction

Interpretation:

The unbranched 1-alkene that will be liquid at room temperature has to be chosen from the given set of options.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkenes are linear chain unsaturated hydrocarbons and cycloalkenes are cyclic carbon chain unsaturated hydrocarbons. They both occur naturally.

Alkenes and cycloalkenes are hydrocarbons. They are nonpolar molecules. Water is a polar molecule. Therefore, alkenes and cycloalkenes do not get solubilized in water. In other words, alkenes and cycloalkenes are insoluble in water.

Regarding density, alkenes and cycloalkenes have density lower than water. When alkenes and cycloalkenes are mixed with water, two layers are formed which is a result of insolubility. Alkenes and cycloalkenes are present on top of water layer which is due to lesser density.

Boiling point of alkenes and cycloalkenes increase with an increase in carbon‑chain length or the ring size. The continuous chain alkenes which contain two to four carbon atoms are gases at room temperature. The continuous chain alkenes that contain five to seventeen carbon atoms and one double bond are liquids at room temperature.

When branching happens in the carbon chain, it lowers the boiling point of alkenes. In simple words, unbranched alkenes have more boiling point than branched alkenes with the same number of carbon atoms.

Cycloalkenes have more boiling point compared to noncyclic alkenes with the same number of carbon atoms. This is due to the more rigid and more symmetrical structures that occur in cyclic systems. Cyclopropene and cyclobutene are relatively unstable compound and gets converted into other hydrocarbons.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13.8, Problem 2QQ

Interpretation Introduction